Synthesis, Characterization and Gas Sensing Performance of PbMnO3, PbMnO3 : SiO2 and PbMnO3 : Al2O3

Authors

  • A. V. Borhade  Research Centre, Department of Chemistry, H.P.T. Arts and R.Y.K. Science College, Nasik, Maharashtra, India
  • S. L. Sangle  Research Centre, Department of Chemistry, H.P.T. Arts and R.Y.K. Science College, Nasik, Maharashtra, India
  • D. R. Tope  Research Centre, Department of Chemistry, H.P.T. Arts and R.Y.K. Science College, Nasik, Maharashtra, India

DOI:

https://doi.org//10.32628/IJSRSET1184111

Keywords:

PbMnO3, XRD; BET, Thick Films, Gas Sensing

Abstract

The present study reports ecofriendly mechanochemical synthesis of PbMnO3, PbMnO3:SiO2 and PbMnO3:Al2O3 composite metal oxides for the first time. The polycrystalline product obtained was analyzed by various physical investigative techniques including FTIR, XRD, SEM, TEM and BET surface area. Screen printed thick films of PbMnO3 and modified PbMnO3 oxides were prepared to check the potential application for gas sensing properties for most toxic, combustible and hazardous gases CO, CO2, H2, Cl2, NH3 and H2S at different operating temperatures ranging from 500C to 400 0C. Among the synthesized sensor PbMnO3:SiO2 shows highest sensitivity (1740) towards NH3 at 50 0C as compared toPbMnO3 (71.42) to NH3 at 200 0C andPbMnO3:Al2O3 (315.8) toH2S at 2500C.This study signifies that sensor was observed to be highly sensitive and selective to NH3 and H2S gas.

References

  1. KA. Seiyama, K. Fujiishi, M. Nagarani, Anal. Chem. 34, 1502 (1962)
  2. N Yamazoe, Y. Kurokawa, T. Seiyam, Sens. Actuators. 4, 283 (1983)
  3. T Kabayashi, M. Haruta, H. Sano, M. Nakane, Sens. Actuators. 13, 339 (1988)
  4. J Tamaki, T. Maekawa, S. Matsushima, N. Miura, N. Yamazoe, Chem. Lett. 19, 477 (1990)
  5. U Lampe, J. Gerblinger, H. Meixner, Sens. Actuators B Chem. 25, 657 (1995)
  6. Y Nakamura, H. Zhang, A. Kishimoto, O. Okada, H. Yanagida, J. Electrochem. Soc. 145, 632 (1998)
  7. W.H. TaO, C.H. Tsai, Sens. Actuators B Chem. 81, 237 (2002)
  8. C. Cantalini, Sens. Actuators B Chem. 24, 1421 (2004)
  9. J.D. Shakun, P.U. Clark, H. Feng, S.A. Marcott, A.C. Mix, L. Zhengyu, B. Bliesner, A. Schmittner, E. Bard, Nature. 49, 484 (2002)
  10. P. Puligundla, J. Jung, S. Ko, Food Control 25, 328 (2012)
  11. G. Eranna, B.C. Joshi, D.P. Runthala, R. Gupta, Crit. Rev. Solid State Mater. Sci. 29, 111 (2004)
  12. T. Yasuda, S. Yonemura, A. Toni, Sensors 12, 3641 (2012)
  13. B. H. Chu, C. Y. Chang, S. J. Pearton, J. Lin, F. Ren eds., Chemical and Biomedical Applications (CRC Press, Boca Ratan, 2011), pp. 47-48
  14. N.T.R.N. Samarasekara, P. Kumara, N.U.S. Yapa, J. Phys. Condens. Matter 18, 2417 (2006)
  15. T. Krishnakumar, R. Jayprakash, T. Prakash, D. Satyaraj, N. Donato, S. Licoccia, M. Latino, A. Stassi, G. Neri Nanotechnology 22, 325501 (2011)
  16. A. Marsal, A. Cornet, J.R. Morante, Sens. Actuators B Chem. 94, 324 (2003)
  17. J. Herran, G.G. Mandayo, E. Castano, Sens. Actuators B Chem. 129, 705 (2008)
  18. C.R. Michel, A.H. Martinez, F.H. Villalpando, J.P.M. Lazaro, J. Alloys Compd. 484, 605 (2009)
  19. G. Sberreglieri, L. Depero, S. Groppelli, P. Nelli, Sens. Actuators B Chem. 89, 26 (1995)
  20. M.S. Wagh, G.H. Jain, D.R. Patil, S.A. Patil, L. A. Patil, Sens. Actuators B Chem. 20, 55 (1994)
  21. C.L. Johnson, J.W. Schwank, K.D. Wise, Sens. Actuators B Chem. 20, 55 (1994)
  22. H. Windichmann, P. Mark, J. Electrochem. Soc. 126, 627 (1979)
  23. K. Wetchokun et al., Sens. Actuators B Chem. 160, 580-591 (2007)
  24. P.E. Caro, J.O. Sowyer, L. Eyring, Spectra Acta28, 1167 (1971)

International Journal of Scientific Research in Science, Engineering and Technology

Downloads

Published

2018-11-30

Issue

Volume 4, Issue 11, November-December-2018

Section

Research Articles

License

Copyright (c) IJSRSET

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
A. V. Borhade, S. L. Sangle, D. R. Tope, " Synthesis, Characterization and Gas Sensing Performance of PbMnO3, PbMnO3 : SiO2 and PbMnO3 : Al2O3, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 4, Issue 11, pp.01-10, November-December-2018. Available at doi : https://doi.org/10.32628/IJSRSET1184111