Synthesis of ZnO nanorods by novel surfactant assisted wet chemical method and its Photocatalytic Activity

Authors

  • V. Shally  Research Department of Physics, Holy Cross College, Nagercoil, Tamil Nadu, India
  • M. Priya Dharshini  Research Department of Physics, Holy Cross College, Nagercoil, Tamil Nadu, India
  • P. Libin Raj   Research Department of Physics, Holy Cross College, Nagercoil, Tamil Nadu, India
  • Sr. Gerardin Jayam  Research Department of Physics, Holy Cross College, Nagercoil, Tamil Nadu, India

Keywords:

Nanorods, Congo Red, Photocatalytic activity, Tauc plot, Band gap

Abstract

In this paper, synthesis of ZnO nanorods is done by a simple and surfactant assisted wet chemical method. The obtained ZnO nanorods can be characterized using various techniques like Powder X-ray Diffraction (PXRD), Field Emission Scanning Electron Microscopy (FESEM) and UV-DRS Spectroscopy. XRD results reveal that the sample is crystalline with a hexagonal wurtzite phase with the particle sizes of 30 nm. Field Emission Scanning Electron Microscopy (FESEM) result reveals that the ZnO nanoparticles are rod like shaped. The band gap of ZnO nanorods were determined from Tauc Plot. The photocatalytic activity of ZnO nanorods has been examined by the degradation of Congo Red dye using UV light.

References

  1. Surabhi Siva Kumar, Putcha Venkateswarlu Vanka Ranga Rao and Gollapalli Nageswara Rao, International NanoLetters,Vol.3:30, PP.1-6, (2013).
  2. X.L. Cheng, H. Zhao, L.H. Huo, S. Gao, J.G. Zhao, Sensors and Actuators B: chemical, Vol. 102, Issue 2, Pages 248- 252, (2004).
  3. S. Y. Lee, E. S. Shim, H. S. Kang, S. S. Pang, Thin Solid Films, Vol. 437, No. 1, PP. 31-34, (2005).
  4. Zhong Lin Wang, ,Xiang Yang Kong ,Yong Ding, Puxian Gao ,William L. Hughes , Rusen Yang and Yue Zhang , Advanced Functional Materials, Vol.14,No.10,PP. 943–956, (2004).
  5. Huang YH, Zang Y, Liu L, Fan SS, Wei Y, He J, Journal of Nanoscience and Naotechnology,Vol.6(3),PP.787–790,(2006).
  6. Michael H. Huang, Samuel Mao, Henning Feick, Haoquan Yan, Yiying Wu, Hannes Kind, Eicke Weber, Richard Russo, Peidong Yang, Science, Vol. 292, PP.1897–1899, (2001).
  7. Lionel Vayssieres, Karin Keis, Anders Hagfeldt, and Sten-Eric Lindquist, Chemistry of Materials, Vol. 13 (12), PP. 4395–4398, (2001).
  8. R. Konenkamp, L. Dloczik, K. Ernst, and C. Olesch , Physica E: Low-Dimensional Systems and Nanostructures, Vol. 14, No. 1-2, PP. 219–223, (2002).
  9. D. Brida, E. Fortunato , H. Aguas, V. Silva, A. Marques, L. Pereira, I. Ferreira, R. Martins, Journal of Non-Crystalline Solids ,Vol .299–302,PP. 1272–1276, (2002).
  10. Zhong Lin Wang, Journal of Physics: Condensed Matter, Vol. 16, PP. R.829 R858, (2004).
  11. M.Suchea,S. Christoulakis , K. Moschovis, N. Katsarakis and G. Kiriakidis , Thin Solid Films, Vol. 515, PP. 551–554, (2006)
  12. A.Ashour, M.A. Kaid, N.Z. El-Sayed, A. A Ibrahim, Applied Surface Science, Vol.252, PP.7844–7848, (2006).
  13. Jyh-Cherg Chen ,Chun-Tien Tang, Journal of Hazardous Materials, Vol.142, Issues 1-2 , PP. 88-96 , (2007).
  14. W. J. E. Beek, M. M. Wienk, and R. A. J. Janssen, AdvancedMaterials,Vol.16, No.12, PP. 1009–1013, (2004).
  15. Morales A.M and Libber C.M, Science, Vol. 279, PP. 208, (1998).
  16. Eric R Waclawik, Jin Chang, Andrea Ponzoni, Isabella Concina, Dario Zappa, Elisabetta Comini, Nunzio Motta, Guido Faglia, Giorgio berveglieri, Beilstein Journal of Nanotechnology, Vol. 3, No. 1, PP. 368–377, (2012).
  17. Prabhakar Rai and Yeon- Tae Yu, Sensors and Actuators B: Chemical, Vol.173, PP.58-65, (2012).
  18. Ziwei Deng , Min Chen, Guangxin Gu and Limin Wu, Journal of Physical Chemistry B, Vol. 112, No. 1, PP. 16–22, (2008).
  19. J. W. Rasmussen, E. Martinez, P. Louka, and D. G. Wingett, Expert Opinion on Drug Delivery,Vol. 7, No. 9, PP. 1063–1077, (2010).
  20. Zhong Lin Wang, Nanostructures of zinc oxide, Materials Today, PP. 26-33, (2004).

Downloads

Published

2017-12-31

Issue

Section

Research Articles

How to Cite

[1]
V. Shally, M. Priya Dharshini, P. Libin Raj , Sr. Gerardin Jayam, " Synthesis of ZnO nanorods by novel surfactant assisted wet chemical method and its Photocatalytic Activity, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 2, Issue 2, pp.269-272, March-April-2016.