Synthesis and Characterization of [(RRTe)2L] and [RRTe.L] Compounds with Macrocyclic Ligands : A Photoelectron Spectroscopic Study

Authors(4) :-Shishir Malviya, Abhishek Kumar, Rajesh Kumar Kushwaha, Shekhar Srivastava

[(RRTe)2.L1], [RRTe.L2] and [RRTe.L3] compounds (where R = R= C6H5CH2 ; p-MeOC6H4 ; R = p-MeOC6H4  & R = p-Me2NC6H4 ; R = p-EtOC6H4 & R = p-Me2NC6H4; R = R= C6H4C6H4) and  L= L1= 3, 6, 9, 12, 20, 23, 26, 29, 35, 36–decaazatricyclo[29.3.1.1] hexatriaconta-1(34), 14, 16, 18(36), 31(35), 32-hexaene-2, 13, 19, 30-tetraone; L2=3, 6, 9, 17, 20, 23, 29, 30- octaazatricyclo [23.3.1.1] triaconta-1 (28), 11, 13, 15(30), 25(29), 26-hexaene-2, 10, 16, 24–tetraone and L3= 3, 7, 15, 19, 25, 26–hexaazatricyclo[19.3.1.1]hexacosa-1(24), 9, 11, 13(26), 21(25), 22–hexaene–2, 8, 14, 20–tetraone have been synthesized and characterized by elemental analysis, molar conductance, I.R. and X-ray photoelectron spectra (XPS) data and an distorted octahedral geometry were established.

Authors and Affiliations

Shishir Malviya
Department of Chemistry, University of Allahabad, Allahabad, Uttar Pradesh, India
Abhishek Kumar
Department of Chemistry, University of Allahabad, Allahabad, Uttar Pradesh, India
Rajesh Kumar Kushwaha
Department of Chemistry, University of Allahabad, Allahabad, Uttar Pradesh, India
Shekhar Srivastava
Department of Chemistry, University of Allahabad, Allahabad, Uttar Pradesh, India

Macrocyclic Ligands, Organotellurium (II), XPS

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Publication Details

Published in : Volume 2 | Issue 4 | July-August 2016
Date of Publication : 2016-08-30
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 517-524
Manuscript Number : IJSRSET1624114
Publisher : Technoscience Academy

Print ISSN : 2395-1990, Online ISSN : 2394-4099

Cite This Article :

Shishir Malviya, Abhishek Kumar, Rajesh Kumar Kushwaha, Shekhar Srivastava, " Synthesis and Characterization of [(RRTe)2L] and [RRTe.L] Compounds with Macrocyclic Ligands : A Photoelectron Spectroscopic Study, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 2, Issue 4, pp.517-524, July-August-2016.
Journal URL : http://ijsrset.com/IJSRSET1624114

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