Synthesis and Antibacterial Application of Nanosized Polyethylene oxide - Iodine Complex by Solid - Vapor Reaction

Authors

  • Ishwar Das  Chemistry Department, Deen Dayal Upadhyaya Gorakhpur University, Gorakhpur, Uttar Pradesh, India
  • Avinash Kumar Pandey  Chemistry Department, Deen Dayal Upadhyaya Gorakhpur University, Gorakhpur, Uttar Pradesh, India
  • Shobhna Dorthy Fredrick  Chemistry Department, St. Andrews College, Gorakhpur, Uttar Pradesh, India
  • Abhishek Kumar Mishra  Chemistry Department, St. Andrews College, Gorakhpur, Uttar Pradesh, India

Keywords:

Poly ethylene oxide, solid-vapor reaction, antibacterial application

Abstract

An eco-friendly reaction between polyethylene oxide (PEO) and iodine vapor has been studied on microslide. Growth kinetics was studied by measuring an increase in weight of the material as a function of time and found to increase non- linearly. Random distribution of iodine in the complex was observed by SEM-EDS studied. UV- visible absorption spectroscopy revealed a new peak at ~ 300 nm due to interaction of iodine with the polymer. Powder x-ray diffraction (XRD) patterns of the reactant and reactant product were compared. Both were found different. Crystallite size of the complex was calculated by using Debye Scherrer formula and found in the range 20-30 nm. The complex was thermally less stable than the reactant. An enhancement in the electrical conductivity was observed on complexation with iodine. SEM results also showed morphological change on complexation. TEM studies revealed the formation of nanosized (<10 nm) complex, in agreement with XRD results. Antibacterial application of the complex was investigated on blood agar containing gram negative bacteria E. coli and no bacterial growth was observed in its presence. It is found to be highly effective against the bacteria E. coli.

References

  1. Elimelch, H.; Avnir, D. 2012, Chemical reactivity of hybrid particles, RSC Adv.2, 863-869.
  2. Nicole, L.; Rozes, L.; Sanchez, C., Intergrative approaches to hybrid multifunctional materials: from multidisciplinary research to applied technologies, 2010, Adv. Mater, 22, 3208.
  3. Farin, D.; Avnir, D., Reactive fractal surfaces, J. Phys. Chem.1987, 91(22), 5517-5521.
  4. Avnir, D.; Farin, D.; Pfeifer, P. 1984, Molecular fractal surfaces, Nature (London), 308, 261.
  5. Meyer, A. Y.; Farin, D.; Avnir, D. 1986, Cross-sectional areas of alkanoic acids. A comparative study applying fractal theory of adsorption and consideration of molecular shape, J. Am. Chem. Soc., 108, 7898.
  6. Rastogi, R. P.; Das, I.; Pushkarna, A. 1991, Fractal like kinetic in solid- gas reaction, Chemical Physics Letters, 186 (1), 1-3.
  7.  Rastogi, R. P.; Dubey, B. L. 1967, Solid- state reaction between iodine and mercurous halide, J. Am. Chem. Soc., 87, 200.
  8.  Rastogi, R. P.; Dubey, B. L.; Lakshmi; Das, I. 1978, Chemistry of mixed halides, J. Scientific & Industrial Research, 37 (11), 622-628.
  9. Agrawal, N. R.; Fredrick, S. D.; Das, I. 2016, A new method of synthesis and characterization of nano-sized mercuric iodide by solid–gas reaction, J. Indian Chem. Soc., 93, 1-5.
  10. Moulay, S. 2013, Molecular iodine/ polymer complexes, J. Polym  Eng., 33(5), 389-443.

Ignatova, M.; Manolova, N.; Rashkov. 2007, Electrospinning of poly(vinyl pyrrolidone)–iodine complex and poly(ethylene oxide)/poly(vinyl pyrrolidone)–iodine complex – a prospective route to antimicrobial wound dressing materials, I. European Polymer Journal, 43(5), 1609-1623.

Wang, Y.; Sotzing, G.A.; Weiss, R. A., 2006, Sorption of iodine by polyurethane and melamine-formaldehyde foams using iodine sublimation and iodine solutions, Polymer,47, 2728-2740.

Kristinsson, K.G.; Jansen, B.; Treitz, U.; Schumacher-Perdreau, F.; Peter, G.; Pulverer, G. 1991, Antimicrobial Activity of Polymers Coated with Iodine-Complexed Polyvinylpyrrolidone, J. Biomater. Appl., 5(3), 173-184.

  1. Das, I.; Kumar, A.; Singh, U. K. 1997, Dynamic instability and non-equilibrium patterns during the growth of E.Coli, Indian J. Chem., 36A, 1018-1022.

International Journal of Scientific Research in Science, Engineering and Technology

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Published

2017-08-31

Issue

Volume 3, Issue 5, July-August-2017

Section

Research Articles

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How to Cite

[1]
Ishwar Das, Avinash Kumar Pandey, Shobhna Dorthy Fredrick, Abhishek Kumar Mishra, " Synthesis and Antibacterial Application of Nanosized Polyethylene oxide - Iodine Complex by Solid - Vapor Reaction , International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 3, Issue 5, pp.242-248, July-August-2017.