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Synthesis and Molecular Structure Analysis of 4-(bis(2-chloroethyl)amino)-3-nitro-2H-chromen-2-one by Single crystal XRD Method

Authors(4):

Nirav Tatamiya, Jayesh S. Babariya, Yogesh T. Naliapara, D. M. Purohit
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A novel 3-nitro and 4-N-mustard functionalized coumarine has been synthesized using 4-chloro, 3-nitro coumarine and Diethanol amine using Isopropyl alcohol as solvent, resultant intermediate undergoes chlorination with Thionyl chloride and DMF as solvent is described. The synthesized compound characterized by spectroscopic techniques and finally confirmed by X-ray diffraction studies. The molecule crystallizes in the monoclinic crystal class in the space group P21/c with cell parameters a = 7.473(1)Aob =   8.169 (1)Ao ,c =  13.957(2)Ao ,a =  87.942(5)Ao ,b =  86.073(5)Ao ,g =  65.040(5)Ao and Z = 4. The Coumarine ring adopts flattened conformation.

Nirav Tatamiya, Jayesh S. Babariya, Yogesh T. Naliapara, D. M. Purohit

3-Nitro-4-Chloro Coumarine, Hydrogen Bonds

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Publication Details

Published in : Volume 3 | Issue 6 | September-October - 2017
Date of Publication Print ISSN Online ISSN
2017-10-31 2395-1990 2394-4099
Page(s) Manuscript Number   Publisher
110-113 IJSRSET173617   Technoscience Academy

Cite This Article

Nirav Tatamiya, Jayesh S. Babariya, Yogesh T. Naliapara, D. M. Purohit, "Synthesis and Molecular Structure Analysis of 4-(bis(2-chloroethyl)amino)-3-nitro-2H-chromen-2-one by Single crystal XRD Method", International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 3, Issue 6, pp.110-113, September-October-2017.
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