Electrochemical Kinetics Study of Ga(III) with Amino Acids at different temperature on dropping mercury electrode (d.m.e)

Authors

  • Jyoti Singh  Department of Chemistry, Uka Tarsadia University, Bardoli, Gujarat, India
  • Sushil Kumar Sharma  Department of Pure & Applied Chemistry, University of Kota, Kota, Rajasthan, India

Keywords:

Ga(III), Serine, d.m.e., Kinetics parameter, Koutecky's method

Abstract

Polarographic behaviour of Ga(III) has been investigated in the presence of amino acids at d.m.e and the reduction of Ga(III) has been found to be irreversible in the presence of supporting electrolyte with or without complexing agent. The complexes of Ga(III) with serine amino acid have been investigated and their kinetics parameters have been evaluated. Transfer coefficient ( and formal rate constant (K◦fh) have been determined in aqueous medium at 308K and 318K by applying Koutecky’s method.

References

  1. J. P. Mother, A.T. Parent, H.  Wolosker, R.O.Brady, C.D. Ferries, M.A. Rogawski, S.H. Synder, Proc. Natel. Acad. Sci., USA, 97(a), 4926-31(2000).
  2. J. Koutcky, Collect Czech.Chem.Commun.,18, 597(1953).
  3. P. Delahy, New Instrumental Methods in Electrochemistry, Inter science publisher, Inc.New York.,(1954).
  4. V. Sharma and K.D. Gupta, J. Electrochem . Soc., India. 2003, 52(1), 20-22.
  5. V.N. Spiridonov, R.K. Astakshova, S.R. Balushkina, Electrokhimiya Russia., 2009,45(2), 131-140.
  6. M.Y. Sreedhar, M. Sankara Nagak, K.S. Prassad, P.R.Prassad and C.N. Reddy, J. Electrochem., India.,2010, 7(1), 166-170.
  7. F. Khan and Rakhi. Agarwal, J.Indian. Chem. Soc.,2009, 86(1), 83-86.
  8. S. Kumar and O.D. Gupta, Int. J. Chem. Sci., 2011, 9(2), 687-698.
  9. G. Battistuzzi, M. Borsari, L. Menabue, M. Saladine and M.Solo, J.Inorg. Climica Act., 1998, 273, 397-402..
  10. C. Karadia, O.D.Gupta, Rasayan J.Chem., 2009, 2(1).
  11. S. Kumar and O.D. Gupta, Oriental  J. Chem., 2011,27.
  12. S. Kumar and O.D.Gupta, Rasayan J.Chem, 2010, 3(3), 581-583.

International Journal of Scientific Research in Science, Engineering and Technology

Downloads

Published

2017-12-31

Issue

Volume 3, Issue 8, November-December-2017

Section

Research Articles

License

Copyright (c) IJSRSET

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
Jyoti Singh, Sushil Kumar Sharma, " Electrochemical Kinetics Study of Ga(III) with Amino Acids at different temperature on dropping mercury electrode (d.m.e), International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 3, Issue 8, pp.378-380, November-December-2017.