An Efficient Synthesis of Biologically Active N-Aryl phthalimides Using DES

Authors

  • Nilesh S. Pawar  Synthetic Organic Research Laboratory, Department of Chemistry, Pratap College, Amalner,t – Jalgaon, Maharashtra, India

Keywords:

Green Chemistry, Deep Eutectic Solvent, Phthalimide, Arylation and Fungicide.

Abstract

The newer view of Deep Eutectic Solvent (DES) in chemistry has number of advantages and one of the promising greener alternatives. We are also report herein catalyst free synthesis of various N-aryl phthalimides compounds using K2CO3+Glycerol as DES.

References

  1. Gruzdyes G. S., Zinchenko V. A. and Slovtsov R. I., in The Chemical Protection of Plants, by G. S. Gruzdyes, Mir Publishers, Moscow, 272 (1983)
  2. Nene Y. L. and Thapliyal P. N., in Fungicides in plant Diease Controll, 3rd Ed., Oxford and IBH Publishing Co. Pvt. Ltd., New Delhi, 170, (1993).
  3. Sree Ramulu U. S., in Chemistry of Insecticides and Fungicides, 2nd Ed., Oxford and IBH Publishing Co. Pvt. Ltd., New Delhi, 246, (1995).
  4. Leonard J., J Nat Prod Rep, 16, 319, (1999).
  5. Chakraborty D. P., In the Alkaloids, Chemistry and Pharmacology, Vol 44, Cordell G A Ed, Academic Press, Inc, Chapt 4, 257-364, (1993).
  6. Knolker H J and Reddy K R, Chem Rev, 102(11), 4303, (2002).
  7. Gribble G W, Synlett, 289, (1991).
  8. Koning C. B. de, Michael J P, Nhlapo J M, Pathak R and Otterlo W A L van, Synlett, 5, 705, (2003).
  9. Joshi B. S., Heterocycles, 3, 837, (1975).
  10. Kawasaki T. and Sakamoto M., J Indian Chem Soc, 71, 443, (1994).
  11. Nefkens G.H.L., Tesser G. I. and Nivard R.J.F., Rec. In Chem., 79, 688 (1960).
  12. Kehler J. and Breuer E., Synthesis, 1419,(1998).
  13. Hajipour A. R., Mallakpour S. E. and Imanzadeh G., Ind. J. Chem., 40B, 250, (2001).
  14. Bogdal D., Pielichowski J. and Boron A., Synlett, 873, (1996).
  15. Tundo P., J. Chem. Soc. Chem. Commun., 641 ,(1977).
  16. Landini D., Rolla F., Synthesis, 389, (1976).
  17. Wolfe S. and Hasan S. K., Can. J. Chem., 48, 3566, (1970).
  18. a) Normant H. and Cavigny T., Bull. Soc. Chim. Fr., 1866, (1965). b) Pawar N. S., Nikumbh V. P. Dalal D. S., More D. H. and Mahulikar P.P., Chemical Weekly, March 15, 195 (2005).
  19. Shoeb, Gearien, J. Pharm. Sci., 51, 469, (1962).
  20. Maulding D. R., Clarke R. A., Roberts B. G. and Rauhut M.M., J. Org. Chem., 33, 250 (1968).
  21. Dictionary of Organic Compounds, 5th and 6th, Ed; Chapmann and Hall, London, (1982) and (1997).
  22. Beilstein Handbook of Organic Chemistry, EII H VI, 526-531.
  23. P.T. Anastas and J.C. Warner, Green Chemistry: Theory and Practice (Oxford University Press, Oxford, 1998)
  24. P.T. Anastas and T. Williamson, Green Chemistry: Frontiers in Benign Chemical Syntheses and Processes (Oxford University Press, Oxford, 1998)
  25. T. Welton, Chem. Rev. 99, 2071 (1999)
  26. D. Zhao, Y. Liao and Z. Zhang, Clean 3, 42 (2007)
  27. M.C. Bubalo, K. Radosevic, I.R. Redovnikovic, J. Halambek and V.G. Srcek, Ecotoxicol. Environ. Saf. 99, 1 (2014)
  28.  A.P. Abbott, D. Boothby, G. Capper, D.L. Davies and R.K. Rasheed, J. Am. Chem. Soc. 126, 9142 (2004)
  29.  C. Ruß, B. Konig, Green Chem. 14, 2969 (2012)
  30. A. Paiva, R. Craveiro, I. Aroso, M. Martins, R.L. Reis and A.R.C. Duarte, ACS Sustain. Chem. Eng. 2, 1063 (2014)
  31. Q. Zhang, K.D.O. Vigier, S. Royer and F. Jerome, Chem. Soc. Rev. 41, 7108 (2012)
  32. B. Tang and K.H. Row, Monatsh. Chem. 144, 1427 (2013)
  33. S.B. Phadtare and G.S. Shankarling, Green Chem. 12, 458 (2010).

International Journal of Scientific Research in Science, Engineering and Technology

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Published

2017-12-31

Issue

Volume 3, Issue 8, November-December-2017

Section

Research Articles

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How to Cite

[1]
Nilesh S. Pawar, " An Efficient Synthesis of Biologically Active N-Aryl phthalimides Using DES, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 3, Issue 8, pp.309-311, November-December-2017.