Corrosion Inhibition Study of Dodecylamine as long Chain Amine Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Solution

Authors(5) :-Vikas, Pradeep Kumar, Gobind Goyat, Suresh Kumar, Hari Om

The corrosion inhibition study by using various concentrations of dodecylamine on mild steel in 1.0 M HCl solution at different temperature i.e. 298, 308 and 318K for immersion time periods of 24.0 hrs were carried out by Weight loss measurement, Electrochemical impedance spectroscopy (EIS), Potentiodynamic polarization measurement, SEM (Scanning Electron Microscope). The results from the weight loss measurement show that corrosion inhibition efficiency increases with increasing the inhibitors concentration but decreases with increasing in temperature range, the maximum percentage corrosion inhibition efficiency were found 88.67% for dodecylamine for 1000 ppm concentration at 298 K temperature for 24 hours. By electrochemical impedance study it observed that charge transfer resistance (Rct) value increases and double layer capacitance (Cdl) value decreases with increasing the inhibitior concentration hence inhibition efficiency increases which also related to the charge transfer resistance. Potentiodynamic polarization curves show that dodecylamine behave as mixed type corrosion inhibitor. Adsorption of studied inhibitor on the mild steel surface obeyed the Langmuir adsorption isotherm. SEM study also analysis that there is formation of protective layer on the surface of mild steel to protect the surface against corrosion and surface become smooth and more clean and clear with increasing the inhibitor concentrations.. Hence all these techniques study shows that dodecylamine is performed as good corrosion inhibitor for Mild Steel in 1.0 M HCl solution.

Authors and Affiliations

Vikas
Department of Chemistry, M. D. University, Rohtak, Haryana, India
Pradeep Kumar
Department of Chemistry, M. D. University, Rohtak, Haryana, India
Gobind Goyat
Department of Chemistry, M. D. University, Rohtak, Haryana, India
Suresh Kumar
Department of Chemistry, M. D. University, Rohtak, Haryana, India
Hari Om
Department of Chemistry, M. D. University, Rohtak, Haryana, India

Mild Steel, Dodecylamine, HCl Solution, Potentiodynamic Polarization, Electrochemical Impedance Spectroscopy, SEM.

  1. Trabanelli, Corros, 1991, 47, 410.
  2. Singh DDN, Singh TB, Gaur B, Corros. Sci, 1995, 37, 1005.
  3. Shaban SM, Aiad I, El-Sukkary MM, Soliman EA, El-Awady MY, J. Mol. Liq, 2015, 203, 2.
  4. Farag AA, Ali TA, J. Ind. Eng. Chem, 2015,21, 627.
  5. Yousefi A, Javadian S, Dalir N, Kakemam J, Akbari J, RSC Adv, 2015, 5, 11697.
  6. Ishwara Bhat J, Vijaya D, Alva P, Arch. Appl. Sci. Res, 2011, 3, 343.
  7. Ostovari SM, Hoseinieh M, Pei Kari SR, Shadizadeh SJ, Hashemi, Corros. Sci., 2009, 51, 1935.
  8. Oguzie EE, Mater. Lett, 2005, 59, 1076.
  9. Larabi L., Harek Y, Traisnel M, Mansria A, J. Appl. Electrochem, 2004, 34, 833.
  10. Samide A, Bibicu I, Rogalski MS, Preda M, Corros. Sci, 2005,47, 1119.
  11. Abdallah M, Corros. Sci, 2004, 46, 1981.
  12. Ashassi-Sorkhabi H, Ghasemi Z, Seifzadeh D, Appl. Surf. Sci, 2005,249, 408.
  13. Samide A, Bibicu I, Surf. Interf. Anal, 2008, 40, 944.
  14. Bentiss F, Lagrene´e M, J. Mater. Environ. Sci, 2011, 2, 13.
  15. Obi-Egbedi NO and Obot IB, Corros. Sci., 2011, 53, 263.
  16. Daoud D, Douadi T, Issaadi S and Chafaa S, Corros. Sci, 2014, 79, 50.
  17. Markhali BP, Naderi R and Mahdavian M, J. Electroanal.Chem, 2014,56, 714.
  18. Hegazy M A, Badawi AM, Abd El Rehim SS and Kamel WM, Corros. Sci, 2013, 69, 110.
  19. Ongun Yuce A, Do?gru Mert B, Kardas G¸ and Yaz?c? B, Corros. Sci, 2014, 83, 310.
  20. Hosseini SMA, Salari M, Jamalizadeh S, Khezripoor S, Seifi M, Mater. Chem. Phys, 2010, 119, 100.
  21. Abdallah M, Helal EA, Fouda AS, Corros. Sci, 2006, 48, 1639.
  22. Khaled KF, Appl. Surf. Sci, 2010, 256, 6753.
  23. Ozcan M, Dehri I, Prog. Org. Coat, 2004,51, 181.
  24. Larabi L, Benali O, Harek Y, Mater. Lett, 2007, 61, 3287.
  25. Abd El-Maksoud SA, Hassan HH, Mater. Corros, 2007, 58, 369.
  26. Mernari B, Attari HEl, Traisnel M, Bentiss F, Lagrenee M, Corros. Sci, 1998, 40, 391.
  27. Umoren SA, Eduok UM, Oguzies EF, Port. Electrochem. Acta, 2008, 26, 533.
  28. Rastoyi RB, Singh MM, Singh K, Yadav M, Port. Electrochem.Acta, 2005, 22, 315.
  29. ASTM G, Standard practice for Laboratory Immersion Corrosion Testing of Metals, ASTM, West Conshohocken, PA, 1990, 31.
  30. Divakara Shetty S, Shetty P, Sudhaker Nayak HV, Indian J. Chem. Technol, 2005, 12, 462.
  31. Muralidharan S, Chandrasekar R, Iyer SVK, Proc. Indian Acad. Sci. (Chem. Sci.), 2000, 12, 127.
  32. Horvath T, Kalman E, Kutsan G and Rauscher A, Br. Corr. J., 1994, 29, 245.
  33. Gunasekaran G, Natarajan R, Muralidharan VS, Palaniswamy N and Apparao BV, Ind. J. Chem. Technol, 1998, 5,
  34. Gunasekaran G, Natarajan R, Muralidharan VS, Palaniswamy N, and Apparao BV, Proc. Ind. Acad. Sci. (Chem.Sci.), 1996, 108, 399.
  35. Wang L, JianYin G and Guo Yin J, Corr. Sci., 2001, 43, 1197
  36. Naqvi I, Saleemi AR, Naveed S, Int. J. Electrochem. Sci, 2011, 6, 146.
  37. Oguzie EE, Unaegbu C, Ogukwea CN, Okolue BN, Onuchuku A I, Mater. Chem. Phys., 2004, 84, 363.
  38. Li XH , Deng SD, Fu H, Corros. Sci, 2012, 62,163.
  39. Bobina M, Kellenberger A, Millet JP, Muntean C, Vaszilcsim N, Corros. Sci., 2013, 69, 389.
  40. Morad M S, J. Appl. Electrochem, 2008, 38, 1509.
  41. Musa AY, Kadhum AAH, Mohamad AB, Rahoma AAB, Mesmari H, J. Mol. Struct.- Theochem, 2010, 969, 233.
  42. Flis J, Zakroczymski T, J. Electrochem. Soc, 1996, 143, 2458.
  43. Khamis E, Bellucci F, Latanision RM, El-Ashry ESH, Corros, 1991, 47, 677.
  44. Obot IB, Obi-Egbedi N O, Umoren SA, Corros. Sci, 2009, 51, 1869.
  45. Cano E, Polo JL, La Iglesia A, Bastidas JM, Adsorption, 2004, 10, 219.
  46. Li W, He Q, Zhang S, Pei C, Hou B, J. Appl. Electrochem., 2008, 38, 289.
  47. Bentiss F, Lebrini M, Lagrenee M, Corros. Sci, 2005, 47, 2915.
  48. Khamis A, Saleh MM, Awad MI, El-Anadouti BE, Corros. Sci, 2013, 74, 83.
  49. Negm NA, Elkholy YM, Zahran MK, Tawfik SM, Corros. Sci, 2010, 52, 3523.
  50. Obi-Egbedi NO, Obot IB, Corros. Sci, 2011, 53, 263.
  51. €Ozcan M, Karadag F, Dehri I, Acta Phys. Chim. Sin, 2008, 24 , 1387.
  52. Wang X, Yang H, Wang F, Corros. Sci, 2011, 53, 113.
  53. Cao CN, Zhang JQ, Science Press, Beijing, 2002, 172 (in Chinese).
  54. Behpour M, Ghoreishi SM, Mohammadi N, Soltani N, Salavati-Niasari M, Corros. Sci, 2010, 52, 4046.
  55. Lebrini M, Lagrene'e M, Vezin H, Traisnel M, Bentiss F, Corros. Sci, 2007, 49, 2254.
  56. Wang X, Yang H, Wang F, Corros. Sci, 2011, 53, 113.
  57. Behpour M, Ghoreishi SM, Soltani N, Salavati-Niasari M, Hamadanian M, Gandomi A, Corros. Sci, 2008, 50, 2172.
  58. Amin MA, Khaled KF, Mohsen Q, Arida HA, Corros. Sci, 2010, 52, 1684.
  59. Qu Q, Jiang SA, Bai W, Li L, Electrochim. Acta, 2007, 52, 6811.
  60. Samardzija KB, Lupu C, Hackerman N, Barron AR, Luttge A, Langmuir, 2005, 21, 12187.
  61. Roy P, Karfa P, Adhikari U, Sukul D, Corros. Sci, 2014, 88, 246.
  62. Solmaza R, Kardas G¸ Ulha MC, Yaz?c? B, Erbil M, Electrochim. Acta, 2008, 53, 5941.
  63. Daoud D, Douadi T, Issaadi S, Chafaa S, Corros. Sci, 2014, 79, 50.
  64. Elayyachy Hammouti B, El Idrissi A, Appl.Surf. Sci, 2005, 249, 176.
  65. Khaled KF, Hackerman N, Electrochim. Acta, 2003, 48, 2715.
  66. Olivares O, Likhanova NV, Gomez B, Navarrete J, Llanos-Serrano ME, Arce E, Hallen JM, Surf. Sci, 2006, 252, 2894.
  67. Zhao J, Duan H, Jiang R, Corros. Sci, 2015, 91, 108.
  68. Quraishi MA, Rafiquee MZA, Khan S and Saxena N, J. Appl. Electrochem, 2007, 37, 1153.
  69. Ahamad I, Prasad R and Quraishi MA, J. Solid State Electrochem, 2010, 14, 2095.
  70. Ferreira ES, Giancomelli C, Giacomelli FC, Spinelli A, Mater. Chem. Phys, 2004, 83, 129.
  71. Li WH, He Q, Pei CL, Hou B R, J. Appl. Electrochem, 2008, 38, 289.
  72. Hegazy MA, Hasan AM, Emara MM, Bakr MF, Youssef AH, Corros. Sci, 2012, 65, 67.
  73. Wang X, Yang H, Wang F, Corros. Sci, 2011, 53, 113.

Publication Details

Published in : Volume 4 | Issue 1 | January-February 2018
Date of Publication : 2018-02-28
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 732-743
Manuscript Number : IJSRSET1841202
Publisher : Technoscience Academy

Print ISSN : 2395-1990, Online ISSN : 2394-4099

Cite This Article :

Vikas, Pradeep Kumar, Gobind Goyat, Suresh Kumar, Hari Om, " Corrosion Inhibition Study of Dodecylamine as long Chain Amine Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Solution, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 4, Issue 1, pp.732-743, January-February.2018
URL : http://ijsrset.com/IJSRSET1841202

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