Spectroscopic and Biological Studies of 3,5-Dichlorosalicylaldehyde-3-Aminopyridine Schiff Base and their Tellurium(IV) Complexes

Authors(5) :-Gobind Goyat, Anju Malik, Vikas, K. K. Verma, Sapana Garg

3,5-Dichlorosalicylaldehyde react with 3-aminopyridine to gives monobasic ON bidentate Schiff base ligand (3-APY-{3,5-ClSalH}). TeCl4, ArTeCl3 and Ar2TeCl2: where Ar = 4-methoxyphenyl, 4-hydroxyphenyl, 3-methyl-4-hydroxyphenyl, react with above Schiff base leads to seven new complexes: having formula [TeCl3(3-APY-{3,5-ClSal})], [ArTeCl2(3-APY-{3,5-ClSal})] and [Ar2TeCl(3-APY-{3,5-ClSal})]. The purity of these compounds was estimated by TLC technique, while their structures were supported by elemental analyses, conductance measurement and spectroscopic methods such as 1HNMR, infrared spectra giving pentacoordinated tellurium centre having ? trigonal bipyramidal geometry. Also, Schiff base ligand and some of their tellurium(IV) complexes display biological activities in vitro against bacteria and fungii.

Authors and Affiliations

Gobind Goyat
Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India
Anju Malik
Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India
Vikas
Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India
K. K. Verma
Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India
Sapana Garg
Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India

3,5-Dichlorosalicylaldehyde, Bidentate Schiff base, Tellurium(IV) Complexes

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Publication Details

Published in : Volume 4 | Issue 1 | January-February 2018
Date of Publication : 2018-02-28
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 755-762
Manuscript Number : IJSRSET1841205
Publisher : Technoscience Academy

Print ISSN : 2395-1990, Online ISSN : 2394-4099

Cite This Article :

Gobind Goyat, Anju Malik, Vikas, K. K. Verma, Sapana Garg, " Spectroscopic and Biological Studies of 3,5-Dichlorosalicylaldehyde-3-Aminopyridine Schiff Base and their Tellurium(IV) Complexes, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 4, Issue 1, pp.755-762, January-February-2018.
Journal URL : http://ijsrset.com/IJSRSET1841205

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