Spectroscopic and Biological Studies of 3,5-Dichlorosalicylaldehyde-3-Aminopyridine Schiff Base and their Tellurium(IV) Complexes

Authors

  • Gobind Goyat  Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India
  • Anju Malik  Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India
  • Vikas  Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India
  • K. K. Verma  Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India
  • Sapana Garg  Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India

Keywords:

3,5-Dichlorosalicylaldehyde, Bidentate Schiff base, Tellurium(IV) Complexes

Abstract

3,5-Dichlorosalicylaldehyde react with 3-aminopyridine to gives monobasic ON bidentate Schiff base ligand (3-APY-{3,5-ClSalH}). TeCl4, ArTeCl3 and Ar2TeCl2: where Ar = 4-methoxyphenyl, 4-hydroxyphenyl, 3-methyl-4-hydroxyphenyl, react with above Schiff base leads to seven new complexes: having formula [TeCl3(3-APY-{3,5-ClSal})], [ArTeCl2(3-APY-{3,5-ClSal})] and [Ar2TeCl(3-APY-{3,5-ClSal})]. The purity of these compounds was estimated by TLC technique, while their structures were supported by elemental analyses, conductance measurement and spectroscopic methods such as 1HNMR, infrared spectra giving pentacoordinated tellurium centre having ? – trigonal bipyramidal geometry. Also, Schiff base ligand and some of their tellurium(IV) complexes display biological activities in vitro against bacteria and fungii.

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International Journal of Scientific Research in Science, Engineering and Technology

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Published

2018-02-28

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Volume 4, Issue 1, January-February-2018

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Research Articles

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[1]
Gobind Goyat, Anju Malik, Vikas, K. K. Verma, Sapana Garg, " Spectroscopic and Biological Studies of 3,5-Dichlorosalicylaldehyde-3-Aminopyridine Schiff Base and their Tellurium(IV) Complexes, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 4, Issue 1, pp.755-762, January-February-2018.