Production and Characterization of Biodiesel-Ethanol-Diesel Blend as Fuel in Compression-Ignition Engine

Authors

  • I. Yahuza  Department of Automobile Engineering, Abubakar Tafawa Balewa University Bauchi, Nigeria
  • S. S. Farinwata  Department of Mechatronics and Systems Engineering, Abubakar Tafawa Balewa University Bauchi, Nigeria
  • H. Dandakouta  Department of Automobile Engineering, Abubakar Tafawa Balewa University Bauchi, Nigeria
  • D. Y. Dasin  Department of Mechanical Engineering, Modibbo Adama University of Technology, Yola

Keywords:

Biodiesel, Transesterification, Ethanol, Fermentation, Staphylococcus Aureus

Abstract

Biodiesel was produced from Neem oil, which was extracted from Neem seed (Azadirachta indica) using Soxhlet extraction by transesterification method. Ethanol was produced from saw dust of Masonia (Masonia Altissama) wood by means of simultaneous saccharification and fermentation process. 7.25liters of oil was recovered from 13.5kg of crushed neem seeds. Using a DMA-35 meter, the sugar produced from the saw dust was measured to be 923.2g and 157.9ml of ethanol was distilled at 780C. The oil, the biodiesel and the blends properties, such as acid value (AV), saponification value (SP), ester value (EV), iodine value (IV), free fatty acid (FFA), peroxide value (PV) and cetane number (CN), were investigated. Total bacterial count and identification of colony growth were conducted and the result shows that Staphylococcus aureus identified with the maximum growth rate of 7 days. The ethanol produced was blended with diesel in different proportions and 10% biodiesel was used as emulsifier to prevent phase separation of the ethanol and diesel. The fuel properties of the biodiesel-ethanol-diesel (BED) blends were also experimentally investigated. The properties determined were relative density, cloud point, pour point, flash point, viscosity and the calorific value. The experimental results of all the blends were compared with standard values to know the suitability of using BED blend in compression ignition engine. The results show that both the relative density and viscosity of the blends decreased as the ethanol content in the blends was increased.

References

  1. Yusuf, A.N., Kamarudin, S.K., Yaakub, Z., (2011). Overview on the current trends in Biodiesel production, Energy Conversion and Management 52, p. 2741.
  2. Daming Huang, Haining Zhou, Lin Lin, (2012). Biodiesel: An Alternative to Conventional Fuel, 2012 International Conference on Future Energy, Environment, and Materials Energy Procedia 16 (2012) 1874 – 1885
  3. Demirbas, A. (2009). Biofuels securing the planet’s future energy needs. Energy Conversion and Management 2009, 50, 2239-2249.
  4. Bull, S.R. (1996). Renewable energy transportation technologies. Renewable Energy 1996, 9, 1019-1024.
  5. Agarwal, A.K. (2007). Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines. Progress in Energy and Combustion Science 2007, 33, 233-271.
  6. Zhou A., Thomson E. (2009). The Development of Biofuels in Asia. Applied Energy 2009, 86, s11-s20.
  7. Apostolakou, A.A.; Kookos, I.K.: Marazioti, C.; Angelopoulos, K.C. (2009). Techno-economic analysis of a biodiesel production process from vegetable oils. Fuel Processing Technology 2009, 90, 1023-1031.
  8. Usta, N.; Oztcurk, E.C.; Can, C.O.; Conkur, E.S.; Nas, S.; Con, A.H.; Can, A.C.; Topcu, M. (2005). Combustion of biodiesel fuel produced from hazelnut soap stock / waste sunflower oil mixture in a diesel engine. Energy Conversion and Management 2005, 46, 741–755.
  9. Hayyan, M.; Mjalli, F. S.; Hashim M.A.; AlNashef, I.M. A (2009). Novel technique for separating glycerin from palm oil-based biodiesel using ionic liquids. Fuel Processing Technology.
  10. Hansen, A. C., Hornbaker, R. H., Zhang, Q., Lyne, P. W. L., (2004). Interest of Combining an Additive with Diesel Ethanol Blends for Use in Diesel Engines; Fuel;80 (4), 565–574.
  11. Honda S. S. and Kaul M. K. (2011): Supplement to Cultivation and Utilization of Medicinal Plants –Regional Research Laboratory, CSIR, Jammu
  12. Qi B. C., Aldrich C, Lorenzen L. and Wolfaardt, G. W. (2005). Acidogenic Fermentation of Lignocellulosic Substrate with Activated Sludge. Chem. Eng. Communications; 192(9): 1221-1242.
  13. Sanchez, O. J. and Cardona, C. A. (2008). Trends in Biotechnological Production of Fuel Ethanol from Different Feedstocks. Bioresource Technology; 99(13): 5270–5295.
  14. Williams, A. G.and Morrison, I.M. (1982). Studies on the Production of Saccharinic Acids by the Alkaline Treatment of Young Grass and their Effectiveness as Substrates for Mixed Remen Microorganisms in Vitro. Journal of the Science of Food and Agriculture;33(1):21–29.
  15. Holtzapple, M. T., Davison R. R., Kaar, W., Chang, N. S.and Loescher, M.E. (1999). Biomass Conversion to Mixed Alcohol Fuels using MixAlco Process. Applied Biochemistry and Biotechnology;79(1-3): 609–631.
  16. William B. Jensen (2007): The Origin of the Soxhlet Extractor Vol. 84 No. 12 December 2007 Journal of Chemical Education 1913.
  17. Zhang, Q. Y., Wu, J. F., Ma, P. H., Cai, J. and Zhang, Y. T. (2015): Acid Value Determination and Pre-Esterification of Crude Euphorbia lathyris L. Oil. World Journal of Engineering and Technology, 3, 70-75. http://dx.doi.org/10.4236/wjet.2015.32007
  18. Lee, A. F., Bennett, J. A., Manayil, J. C., and Ma, P. H. (2014): Heterogeneous Catalysis for Sustainable Biodiesel Production via Esterification and Transesterification. Chemical Society Reviews, 43, 7887-7916. http://dx.doi.org/10.1039/C4CS00189C
  19. Zhang, Q. Y., Li, H., Qin, W. T., Ma, P. H., and Cai, J. (2013): Solid acid Used as Highly Efficient Catalyst for Esterification of Free Fatty Acids with Alcohols. China Petroleum Processing and Petrochemical Technology, 15, 19-24.http://www.cqvip.com/QK/84331X/201301/46399418.html
  20. Sun, J., Yang, J. Y., Li, S. P., and Mu M. (2015) Preparation and Characterization of Fluorine Modified Oxides for Transesterification. Catalysis Communications, 59, 88-91. http://dx.doi.org/10.1016/j.catcom.2014.09.014
  21. Stamper, D., Montgomery, M., Morris, R., (2011). Bio-fouling of Several Marine Diesel Fuels. DTIC Document.
  22. Passman, F., 2001. Recovery of micro algal biomass and metabolites, process options and economics. Biotechnology Advances 20, pp491–515.
  23. Rocheleau, R. E., Bender, G., Virji, M., Antal Jr, M. J., Cooney, M. J., Liaw, B. Y., Masutani, S. M., (2009). Hawaii Energy and Environmental Technologies (HEET) Initiative. DTIC Document.
  24. Hansen, A.C., Hornbaker, R. H., Zhang, Q., Lyne, P. W. L. (2001). On farm Evaluation of Diesel Fuel Oxygenated with Ethanol. ASAE Paper No. 01-6173. ASAE, St. Joseph, MI.
  25. Ajav, E. A. and Akingbehin, O. A. (2002). Biodegradability Characteristics of Current and NewlyDeveloped Alternative Fuels. SAE Technical Paper 1999-01-3518.
  26. Varde, K. S. (1984). Soy Oil Sprays and Effects on Engine Performance. Transactions of the ASAE. 27(2): 326-330, 336.
  27. Msipa, C. K. M., Goering, C. E. and Karcher, T. D. (1983). Vegetable oil Atomization in a Diesel Engine. Transactions of the ASAE;26(6): 1669-1672.
  28. Bansal, B., and Juneja, N. N. (1989). Performance Evaluation of Neem Oil as Diesel Engine Supplementary Fuel. Proceeding of the 11th International Congress in Agric. Engineering Vol. 4, pp. 2551-1556.
  29. Musjuki, H., Abdulmuin, M. Z. and Sii, H. S. (1996). Investigations on Palm oil Methly Esters in the Diesel Engine. Proc. Institution of Mech. Engineers. Part A: Journal of Power and Energy;210:131-138.

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Published

2018-02-28

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Research Articles

How to Cite

[1]
I. Yahuza, S. S. Farinwata, H. Dandakouta, D. Y. Dasin, " Production and Characterization of Biodiesel-Ethanol-Diesel Blend as Fuel in Compression-Ignition Engine, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 4, Issue 1, pp.1415-1424, January-February-2018.