Structural, Optical, Mechanical Studies of Guanidine Tartarate Single Crystals

Authors(4) :-D. Sathya, V. Sivashankar, D. PremAnand, R. Murugesan

Good quality novel organic Guanidine tartarate has been grown from the aqueous solution by low temperature solution growth method. X-ray diffraction reveals that the crystal crystallises into orthorhombic system with noncentrosymmetric space group P212121. The functional groups present in the grown crystal were confirmed by Fourier transform infrared spectral analysis. Ultraviolet– visible-near infra-red absorption studies on this crystal reveal that the cutoff region is around 235 nm. The optical band gap of the crystal was found to be 4.07 eV. Photoluminescence studies show that the material emits violet fluorescence. The mechanical behavior of the title compound was analyzed by Vickers’s microhardness test.

Authors and Affiliations

D. Sathya
Department of Physics, St. Xavier’s College, Palayamkottai, Tirunelveli, Tamilnadu, India
V. Sivashankar
Department of Chemistry, TDMNS College, T. Kallikulam, Tirunelveli, Tamilnadu, India
D. PremAnand

R. Murugesan

X-ray Diffraction, Band Gap, Guanidine, Photoluminescence.

  1. Kalaivanan. R, Srinivasan. K Synthesis, growth and characterization of organic nonlinear optical material: N-benzyl-2-methyl-4-nitroaniline (BNA) Opt. Laser Technol. 90 2017: pp. 27-32.
  3. Eimeral, D., Velsko, S., Davis, L., Wang, F., Progress in nonlinear optical materials for high power lasers. Prog. Cryst. Growth Charact. 20 1990: pp. 59-113.
  4. Yutaka Uematsu, Tsuguo Fukuda, Nonlinear Optical Properties of KNbO3 Single Crystals Jpn. J. Appl. Phys. 10 1971: pp. 507.
  5. NazirAhmad, Ahmad.M.M., Kotru.P.N., Single crystal growth by gel technique and characterization of lithium hydrogen tartrate J. Cryst. Growth 412 2015: pp.72-79.
  6. RO.MU. Jauhar, S. Kalainathan, P. Murugakoothan, Three dimensional organic frame work of 2-amino 4, 6 dimethoxypyrimidine p-toluenesulfonic acid monohydrate: synthesis, single crystal growth and its properties J. Cryst. Growth 424 2015: pp.42-48.
  7. P.Baskaran, M.Vimalan, P.Anandan, G.Bakiyaraj, K.Kirubavathi, K.Selvaraju, Synthesis, growth and characterization of a nonlinear optical crystal: L-Leucinium perchlorate J Taibah univ. Sci. 11(1) 2017: pp.11-17.
  8. Beatrice Fraboni, Alessandro Fraleoni- Morgera, Yves Geerts, Alberto Morpurgo, Vitaly Podzorov, Organic Single Crystals: An Essential Step to New Physics and Higher Performances of Optoelectronic Devices Adv. Func. Mater. 26(14) 2016: pp.2229-2232.
  9. M. Drozd, Molecular structure and infrared spectra of guanidinium cation A combined theoretical and spectroscopic study J. Mater. Sci. Engg 136 2007: pp.20-28.
  10. Graham smith, Urs D. Wermuth, David J. Young, Jonathan M. White, Bis (guanidinium) pyrazine-2,3-dicarboxylate trihydrate Acta. Cryst. E62 2006: pp.o3912-o3914.
  11. D. Sathya, V. Sivashankar, Growth and characterization of a new organic NLO crystal: Guanidineacetate single crystals Optik 126 2015: pp.5873- 5876.
  12. D. Sathya, V. Sivashankar, S. Anbarasu, D. Prem Anand, Study on second order nonlinear properties of organic material: guanidine hydrogen maleate single crystals Inter. J Scientific Res. Modern Edu. (IJSRME) 1(1) 2016: pp.597-606.
  13. D. Sathya, V. Sivashankar, D. Prem Anand, Growth and characterization of Guanidine benzoate (GuBzt)single crystals International Research Journal of Engineering and Technology (IRJET) 4(9) 2017: pp.159-163.
  14. D. Sathya, S. Anbu Radhika, V.Sivashankar, D. PremAnand, Antibacterial Activities of Guanidine Family Single Crystals against Bacillus Subtilis and Staphylococcus Aerus Journal of Physical, chemical and biological sciences 8 (1) 2017: pp.46-50.
  15. J. Zyss, J. Pecaut, J. P. Levy, R. Masse, Synthesis and characterization of guanidine l-monohydrogen tartarate single crystals Acta. Cryst. B49 1993: pp.334-342.
  16. T. Arumanayagam, P. Murugakoothan, Optical and electrical properties of a new organic nlo crystal: guanidinium l-monohydrogentartrate l-tartaric acid Optoelectron. Adv. Mater. 6(1-2) 2012: pp.263 - 265.
  17. D.Sathya, V.Sivashankar, Growth and thermal, micro hardness and NLO studies of guanidinium L-monohydrogentartrate L-tartaric acid (GuHTT) single crystals Inter. J. ChemTech Res.6(3) 2014:pp.1796-1799.
  18. Socrates, G., Infrared and Characteristic Group Frequencies, John Wiley & sons: Singapore 1980.
  19. D.Sathya, V. Sivashankar, M.Durgairaj, R. Murugesan, Third Harmonic Generation of Methylammonium Tetrachloro Zincate [MATC-Zn] Semiorganic NLO Single Crystals, IJSART 3(10) 2017: pp.137-143.
  20. Eya DDO, Ekpunobi AJ, Okeke CE., Influence of thermal annealing on the optical properties of tin oxide thin films prepared by chemical bath deposition technique Acad Open Internet J 17 2006, pp.1311-4360.
  21. F. Yogam, I.V. Potheher, A. Cyrac Peter, S. Tamilselvan, A. Leo Rajesh, M.Vimalan, P. Sagayaraj, Growth and characterization of novel semiorganic nonlinear optical crystals of L-phenylalanine hydrochloride (LPHCl) Adv. Appl. Sci. Res. 2 2011: pp.261-268.
  22. Renuka N, Ramesh Babu R, Vijayan N, Vasanthakumar G, Krishna A, RamamurthiK, Structural, Optical, Mechanical and Dielectric Studies of Pure and doped L Prolonium Trichloroacetate Single Crystals Spectrochim. Acta 137 2015:pp.601.
  23. D. Bharath, S.Kalainathan, Dielectric, optical and mechanical studies of phenolic polyene OH1 organic electro optic crystal Opt. Laser. Technol. 63 2014: pp.90-97.
  24. Y. B. Rasal , R. N. Shaikh , M. D. Shirsat, S. Kalainathan , S. S. Hussaini, Influence of Bis Thiourea Nickel Nitrate on structural, optical, electrical, thermal and mechanical behavior of KDP single crystal for NLO applications Mater. Res. Express 4 2017: pp.03620.

Publication Details

Published in : Volume 4 | Issue 1 | January-February 2018
Date of Publication : 2018-02-28
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 393-399
Manuscript Number : IJSRSET184166
Publisher : Technoscience Academy

Print ISSN : 2395-1990, Online ISSN : 2394-4099

Cite This Article :

D. Sathya, V. Sivashankar, D. PremAnand, R. Murugesan, " Structural, Optical, Mechanical Studies of Guanidine Tartarate Single Crystals, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 4, Issue 1, pp.393-399, January-February-2018.
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