Acoustical Study of Intermolecular Interaction in Mixture of 1-chlorobutane with Benzene and Chlorobenzene
Keywords:
Ultrasonic Velocity, Excess Parameters, Molecular Interaction, Binary Liquid Mixtures.Abstract
The density and ultrasonic velocity of 1-Chlorobutane with Benzene and Chlorobenzene has been taken in different molar concentrations at temperatures 303.16K From the above data excess parameters such as excess adiabatic compressibility (?E) and excess volume (VE) has been evaluate. The presence of hetero-molecular AB interactions is reflected through the excess parameter such as excess compressibility (?aE) and excess volume (V E) . For understanding the nature and strength of hetero-molecular interactions, only two parameters ?aE and VE are considered simultaneously. These excess parameters are used to discuss an intermolecular interaction in system. The study reveals that interaction is maximum in the category polar- polar mixture.
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