Inhibitive effect of 8-hydroxy Quinoline on the corrosion of mild steel in 1M HCl

Authors

  • R. S. Dubey  Department of Chemistry, R. Jhunjhunwala College, Ghatkopar (W), Mumbai , Maharashtra, India
  • Pratap Kamble   Department of Chemistry, R. Jhunjhunwala College, Ghatkopar (W), Mumbai , Maharashtra, India

Keywords:

Mild Steel, Corrosion, HCl, SEM, EDX.

Abstract

The inhibitive action 8-Hydroxy quinoline on corrosion of mild steel in 1 M HCl was investigated by weight loss, open circuit potential (OCP) and potentiodynamic polarization technique. The results showed that the 8-hydroxy Quinoline inhibited mild steel corrosion and inhibition efficiency increased with increase in concentration of inhibitor. The adsorption is spontaneous and followed Langmuir’s adsorption isotherm. Polarization study indicated that the inhibitor acted as mixed-type. The protective film formed on surface is confirmed by scanning electron microscopy (SEM) and energy dispersive analysis by X-ray (EDX).Result obtained from weight loss technique are in good agreement with electrochemical and surface analytical results.

References

[1] W. Machu, in: Proceedings of the Third European Symposium on Corrosion Inhibitors, Ferrara, Italy, University of Ferrara, 1970, p. 107.
[2] F. Bentiss, M. Traisnel, M. Lagrene´e, Corros. Sci. 42 (2000) 127.
[3] A. Chetouani, A. Aouniti, B. Hammouti, N. Benchat, T. Benhadda, S.Kertit, Corros. Sci. 45 (2003) 1675.
[4] M. Lagrene´e, B. Mernari, N. Chaibi, M. Traisnel, H. Vezin, F. Bentiss, Corros. Sci. 43 (2001) 951.
[5] S.S. Abd El-rehim, S.A.M. Refaey, F. Taha, M.B. Saleh, R.A. Ahmed, J. Appl. Electrochem. 31 (2001) 429.
[6] A.B. Tadros, B.A. Abd El-nabey, J. Electroanal. Chem. 246 (1988) 433.
[7] H. Luo, Y.C. Guan, K.N. Han, Corrosion 54 (1998) 721.
[8] S.T. Arab, E.A. Noor, Corrosion 49 (1993) 122.
[9] F. Bentiss, M. Traisnel, N. Chaibi, B. Mernari, H. Vezin, M. Lagrene´e, Corros. Sci. 44 (2002) 2271.
[10] K. Tebbji, H. Oudda, B. Hammouti, M. Benkaddour, M. El Kodadi,
F.Malek, A. Ramdani, Appl. Surf. Sci. 241 (2005) 326.
[11] M. Bouklah, A. Attayibat, S. Kertit, A. Ramdani, B. Hammouti, Appl.
Surf. Sci. 242 (2005) 399.
[12] S. Muralidharan, K.L.N. Phani, S. Pitchumani, S. Ravichandran, S.V.K. Iyer, J. Electrochem. Soc. 142 (1995) 1478.
[13] E.E. Oguzie, V.O. Njoku, C.K. Enenebeaku, C.O. Akalezi, C. Obi, Effect of hexamethyl pararosaniline chloride (crystal violet) on mild steel corrosion inm acidic media, Corros. Sci. 50 (2008) 3480–3486.
[14] V. R. Saliyan, A. V. Adhikari, Quinolin-5-ylmethylene-3-{[8-(trifluoromethyl)quinolin-4-yl] thio} propanohydrazide as an effective inhibitor of mild steel corrosion in HCl solution, Corros. Sci. 50 (2008) 55–61.
[15] K. C. Emregal, O. Atakol, Corrosion inhibition of mild steel with
Schiff base compounds in 1 M HCl, Material Chem. Phys. 82, issue 1
(2003) 188-193.
[16] F. Kandemirli, S. Sagdin, Theoretical study of corrosion inhibition of amides and thio semicarbazones, Corros. Sci. 49 (2007) 2118–2130.
[17] N. Hackerman, R.M. Hurd, in: Proc. Int. Congress of Metallic Corrosion, Butterworths, London, 1962, p. 166.
[18] F.B. Growcock, W.W. Frenier, V.R. Lopp, in: Proc. 6th European Symposium on Corrosion Inhibitors, Ann. Univ. Ferrara, N.S., Sez, V. Suppl. No. 7, 1980, p. 1185.
[19] D. Jayaperumal, S. Muralidharan, P. Subramanium, G. Venkatachari, S. Senthilrel, Anti-Corros. Methods Mater. 44 (1997) 265.
[20] Yiwei Ren, Yi Luo, Kaisong Zhang, Gefu Zhu, Xiaolin Tan, Lignin terpolymer for corrosion inhibition of mild steel in 10% hydrochloric acid medium, Corros. Sci. 50 (2008) 3147–3153.
[21] B.S.Furniss,A.J.Hannaford, P.W.G.Smith, A. R. Tatchell, Vogel’s textbook of practical organic chemistry, fifth edition 1989.
[22] Fouda A. S, Shalabi K, E- Hossiany A,(2016), Moxifloxacine antibiotic as green corrosion inhibitor for carbon steel in 1 M HCl.J.Bio. Tribo .corros.2:18.DOI 10.1007//s40735-016-0048-x.
[23] Ahamad I, Prasad R,Qurashi MA,(2010), Thermodynamic, electrochemical and quantum chemical investigation of some Schiff bases as corrosion inhibitors for mild steel in hydrochloric acid solutions. Corros. Sci.52,933-942.
[24] Elyn Amira WAW, Rahim AA, Osman H, Awang k, Bothi Raja P.(2011),Corrosion inhibition of mild steel in 1M HCl solution by Xylopia Ferruginea Leaves from different extract and partitions.Int .J.Electrochem .Sci.6, 2998-3016.
[25] Wang X,Wan Y, Zeng Y,GuY(1012), Investigation of benzimidazole compound as a novel corrosion inhibitor for mild steel in hydrochloric acid solution . Int.J.Electrochem.Sci.7 ,2403-2415.
[26] ChandrabhanVarma. A.Qurashi, A.Singh(2016), 5-substituted 1H-tetrazoles as effective corrosion inhibitors for mild steel in 1M hydrochloric acid. Journal of Taibah University for science 10,718-733.

Downloads

Published

2018-02-28

Issue

Section

Research Articles

How to Cite

[1]
R. S. Dubey, Pratap Kamble , " Inhibitive effect of 8-hydroxy Quinoline on the corrosion of mild steel in 1M HCl, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 5, Issue 4, pp.103-107, January-February-2018.