Studies of Thermo-acoustical Properties of Polyoxyethylene (20) cetyl ether (Brij-58) in Presence of Additives at Different Temperatures

Authors

  • B. B. Patil  Department of Chemistry, Kisan Arts, Commerce and Science College, Parola, Jalgaon, India
  • G. H. Sonawane  Department of Chemistry, Kisan Arts, Commerce and Science College, Parola, Jalgaon, India

DOI:

https://doi.org//10.32628/IJSRSET207212

Keywords:

Nonionic Surfactant, PVP, PEO, Ultrasound Velocity, Density.

Abstract

The measurement of ultrasonic velocity and density as a function of temperature and concentration of additives were carried out. The variation of ultrasonic velocity and density of micellar solution of Polyoxyethylene (20) cetyl ether (Brij-58, CMC= 0.0086% w/v) in the presence of polymer PVP and PEO were studied at 298.15, 303.15, 308.15 and 313.15K. Various acoustic parameters such as adiabatic compressibility (?ad), molar volume (Vm), intermolecular free length (Lf), acoustic impedance (Z) and surface tension (?) of aqueous solution of Brij-58 and Brij-58-polymer mixed solutions were derived from these data. The results were discussed on the basis of polymer-surfactant interactions and hydrophobic interaction, which in turn depends upon the structural arrangement of the linkages involved and difference in the chain which binds the hydrophobic and hydrophilic group in the studied surfactant molecule. It was noted that the ultrasound velocity decreases with increase in temperature. The decrease in the value of ?ad and Lf with increase in ultrasonic velocity indicates that there is significant interaction between the surfactant molecule and added polymer PVP and PEO.

References

  1. N. Kosaric “Biosurfactants in industry Pure Appl. Chem.”, 1992, 64 (11), 1731-1737, doi.org/10.1351/pac199264111731
  2. Mohd. Sajid Ali, Goutam Ghosh, Kabir-ud-Din. “Amphiphilic drug persuaded collapse of polyvinylpyrrolidone and poly(ethylene glycol) chains: A dynamic light scattering study”, Colloids and Surfaces B: Biointerfaces 2010, 75 (2),590-594, doi:10.1016/j.colsurfb.2009.10.002
  3. Cahn, A. , and Lynn J. . Encyclopedia of Technical Technology, 1981 , 332 , Wiley- Interscience, New York .
  4. Goddard and Ananthapadmanaban, “Interactions of Surfactants with Polymers and Proteins”,1993, CRC Press, Boca Raton, FL, 1993, 1-427.
  5. I. De Simone, N. Coceani, R. Farra, S. M. Fiorentino, G. Grassi, R. Lapasin, D. Hasa, B. Perissutti, M. Grassi, D. Voinovich, “Study on Polymer-SurfactantInteractions for The Improvement of Drug Delivery Systems Wettability”, Chem. Biochem. Eng. 2012, Q. 26 (4) 405–415.
  6. J.C.T. Kwak, “Polymer-surfactant systems”, Dekker, New York, 1998.
  7. A. Avranas, P. Iliou. “Interaction between hydroxypropylmethylcellulose and the anionic surfactants hexane-, octane-, and decanesulfonic acid sodium salts, as studied by dynamic surface tension measurements”. J. of Colloid and Interface Sci. 2003, 258 (1) , 102-109. doi: 10.1016/S0021-9797(02)00129-7
  8. Qi, S., Roser, S., Edler, K.J. et al. “Insights into the Role of Polymer-Surfactant Complexes in Drug Solubilisation/Stabilisation During Drug Release from Solid Dispersions”, Pharm Res 2013, 30, 290–302. doi.org/10.1007/s11095-012-0873-7.
  9. Kawai, .F. “Microbial degradation of polyethers”, Appl Microbiol Biotechnol 2002, 58, 30– 38, doi: 10.1007/s00253-001-0850-2.
  10. Cabane B. “Structure of some polymer-detergent aggregates in water” J. Phys. Chem.1977, 81, 17, 1639-1645, doi: 10.1021/j100532a008
  11. Philip, J.; Prakash, G. G.; Jaykumar, T.; Kalynasundaram, P.; Mondain Monval, O.; Raj, B. “Interaction between Emulsion Droplets in the Presence of Polymer−Surfactant Complexes”, Langmuir 2002, 18, 4625−4631, doi: 10.1021/la0256477.
  12. Anis A. Ansari, M. Kamil, Kabir-ud-Din. “Polymer-Surfactant Interactions and the Effect of Tail Size Variation on Micellization Process of Cationic ATAB Surfactants in Aqueous Medium”, Journal of Dispersion Science and Technology 2013, 34 (5) , 722-730. doi: 10.1080/01932691.2012.685850.
  13. O.Nomoto, J. Phy. Soc. Japan. 1953, 8, 553.
  14. B.S.Bhadane, T.J.Patil, “Micellization studies on binary mixture of methionine with Polyoxyethylene (10) Cetyl Ether (Brij-56) and Polyoxyethylene (20) Cetyl Ether (Brij-58)”, E-Journal of Chemistry, 2010, 7(4), 1578-1583. doi: 10.1155/2010/150425
  15. S. Backlund, H. Hoiland, O.J. Kvammen, and E. Ljosland, “An Ultrasonic Study of Sphere to Rod Transitions in Aqueous Solutions of Hexadecyl trimethyl ammonium Bromide”, Acta Chem. Scand., 1982 A36, 698-700. doi: 10.3891/acta.chem.scand.36a-0698.
  16. H. Høiland, K. Veggeland, S. Backlund, “Structural Changes in Aqueous Micellar Systems of an Anionic or a Cationic Surfactant”, Surfactants in Solution. Springer, 1986, 309-316, doi: 10.1007/978-1-4613-1831-6_23
  17. D. Bala Karuna Kumar, K Rayapa Reddy, G Srinivasa Rao, G. V. Rama Rao and C. Rambabu, “Ultrasonic investigation of molecular associations in the binary mixtures of NMP with substituted benzenes at 308.15, 318.15K and atmospheric pressure”, J. Chem. Pharm. Res., 2011,3 (5), 274-280,
  18. F. M. Sannaningannavar, B. S. Navati, and N. H. Ayachit, “Studies on thermo-acoustic parameters in the dilute solutions of poly(ethyleneglycol)” Polymer Bulletin, 2013, 70, (2), 603–618,. doi: 10.1007/s00289-012-0881-0.
  19. G. Zhao, C.C. Khin, and S. B. Chen, “Nonionic Surfactant and Temperature Effects on the Viscosity of Hydrophobically Modified Hydroxyethyl Cellulose Solutions”, J. Phys. Chem. B, 2005,109,14198-14204. doi.org/10.1021/jp051955c.
  20. K. Sreekanth, D. S. Kumar, “Study of molecular interactions in the mixtures of secondaryalcohols with equimolar mixture of ethanol + formamide from acoustic and thermodynamic parameters” J. Chem. Pharm. Res., 2011, 3(4), 29-41.
  21. H. Eyring, J.F. Kincaid, J. Chem. Phys., 1938, 6, 620.
  22. Aashees Awasthi, J.P. Shukla, “Ultrasonic and IR study of intermolecular association through hydrogen bonding in ternary liquid mixtures” J. Mol. Liq., 2003, 41, 477,. doi: : 10.1016/S0041-624X(03)00127-6
  23. P. S. Nikam, T. R. Mahale, M. Hasan, “Ultrasonic study of alkanols (C1–C4) in binary mixtures containing ethyl acetate as common component’, Acustica, 1998, 84(3), 579-584.
  24. M. Hasan, U. B. Kadam, A. P. Hiray, A. B. Sawant, “Densities, Viscosities, and Ultrasonic Velocity Studies of Binary Mixtures of Chloroform with Octan-1-ol and Decan-1-ol at (303.15 and 313.15) K”, J. Chem. Eng. Data., 2006, 51, 1797- 1801, doi.org/10.1021/je060192z
  25. P. S. Nikam, R. P. Shewale, A.B. Sawant, M. Hasan, “Limiting Ionic Partial Molar Volumes and Viscosities of Cs+, Na+, (C4H9)4N+, Cl-, Br-, I,-, and BPh4- in Aqueous Acetone at 308.15 K”, J. Chem. Eng. Data., 2005, 50, 487- 491, doi.org/10.1021/je049698c.
  26. Chauhan, S., Singh, R., Sharma, K. and Kumar, K.: “Interaction Study of Anionic Surfactant with Aqueous Non?Ionic Polymers from Conductivity, Density and Speed of Sound Measurements”, J. of Surfactants and Detergents, 2015, 18, 2, 225-232. doi:10.1007/s11743-014-1613-2.
  27. Punitha S. and Uvarani R., Molecular interactions of surfactants with polymer in aqueous solutions, J. of Chemical and Pharm. research, 2012, 4, 387-392.
  28. Nithiyanantham, S. and Palaniaappan, L.: Arabian Journal of Chemistry, 2012, 5, (1) 25-30.
  29. Bedare, G. R., Bhandakkar, V. D. and Suryavanshi, B. M.: “Ultrasonic Study of Molecular Interactions in Binary Mixtures at 308 K”, Euro. J. Appl. Eng. Sci. Res., 2012, 1 (1):1-4.
  30. Priya, C. S., Nithya, S., Velraj, G. and Kanappan, A.N., “Molecular interactions studies in liquid mixture using Ultrasonic technique”, Int. J. of Advanced Sci. and Tech., 2010, 18, 59-74.
  31. Ravichandran, S. and Kumari, C.R.T.: E-Journal of Chemistry, 8, 1, 2011, 77- 84.
  32. Frindi, M., Michels, B. and Zana, R. “Ultrasonic absorption studies of surfactant exchange between micelles and bulk phase in aqueous micellar solutions of nonionic surfactants with a short alkyl chain. 2. C6E3, C6E5, C8E4, and C8E8” J. of Phy. Chem., 1992, 96(14), 6095-6102. doi: 10.1021/j100193a082.
  33. Horiuchi, S. and Winter, G. “CMC determination of nonionic surfactants in protein formulations using ultrasonic resonance technology”. Eur J Pharm Biopharm. 2015, 92, 8-14. doi: 10.1016/j.ejpb.2015.02.005.
  34. P. P. Patil V. R. Shaikh, P. D. Patil, A. U. Borse and K. J. Patil, “Volumetric, isentropic compressibility and viscosity coefficient studies of binary solutions involving amides as a solute in aqueous and CCl4 solvent systems at 298.15 K”, J Molecular Liquids, 2018, 264, 223-232,. doi:10.1016/j.molliq.2018.05.062.
  35. T.J.Patil, “Ultrasonic studies on the micellar behaviour of non-ionic surfactant in aqueous polyelectrolyte at 303 and 313 K”, Asian J. of Chemistry, 2008, 20(6), 4383-4387.
  36. T.J.Patil, H. A. Patil, “Ultrasonic and viscometric studies of the behaviour of cetyltrimethyl ammonium bromide in aqueous polyacrylamide at different temperatures”, Asian Journal of Chemistry, 2005,17(3):1979-1983 ·
  37. S.L.Abd-EL-Messigh, Indian Journal Physics, 1996, 70B(2), 119.
  38. S. Chauhan, M. S. Chauhan , G. S. Chauhan , Sonika,J. Jyoti, “Sound Speed and Density Studies of Interactions Between Cationic Surfactants and Aqueous Gelatin Solution”, Int. J. of Thermophysics, 2012, 33(2), 279-288. doi:10.1007/s10765-011-1146-0.
  39. A. A. Patil, Chem. Sci. Rev. and Lett., 2015, 4(13) 25-30.
  40. P. S. Ramesh, D. Gitta, C. Rakkappal, “Ultrasonic studies on aqueous polyethylene oxide in n-alkanols”, J. Mole. Liquids, 2006, 126, 69-71. doi:10.1016/j.molliq.2005.09.006.
  41. S. Velmourougan, J.K.Nambinarayanan, A.S. Rao, B. Krishnan, Indian J. Phys. 61B 1987, 105.
  42. V.K. Syal, Uma Kumari, Suvarcha Chauhan and M.S. Chauhan, Indian J. Pure and Appl Phys., 1992,30, 719.
  43. Rathina K. “Ultrasonic Velocity and Compressibility Variation in Inorganic Sulphates with Aqueous Polymer Solutions” Int. J. Res. Chem. Env. 2015, 5(4), 76-79.
  44. M. Hasan, U. B. Kadam, A. P. Hiray, A.B. Sawant, “Densities, Viscosities, and Ultrasonic Velocity Studies of Binary Mixtures of Chloroform with Pentan-1-ol, Hexan-1-ol, and Heptan-1-ol at (303.15 and 313.15) K” J. Chem. Eng. Data., 2006, 51, 1797-1801, doi: 10.1021/je0504459.

International Journal of Scientific Research in Science, Engineering and Technology

Downloads

Published

2019-05-30

Issue

Volume 6, Issue 3, May-June-2019

Section

Research Articles

License

Copyright (c) IJSRSET

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
B. B. Patil, G. H. Sonawane, " Studies of Thermo-acoustical Properties of Polyoxyethylene (20) cetyl ether (Brij-58) in Presence of Additives at Different Temperatures, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 6, Issue 3, pp.377-389, May-June-2019. Available at doi : https://doi.org/10.32628/IJSRSET207212