Synthesis and Characterization of [(RR’Te)2L] and [RR’Te.L] Compounds with Macrocyclic Ligands : A Photoelectron Spectroscopic Study

Authors

  • Shishir Malviya  Department of Chemistry, University of Allahabad, Allahabad, Uttar Pradesh, India
  • Abhishek Kumar  Department of Chemistry, University of Allahabad, Allahabad, Uttar Pradesh, India
  • Rajesh Kumar Kushwaha  Department of Chemistry, University of Allahabad, Allahabad, Uttar Pradesh, India
  • Shekhar Srivastava  Department of Chemistry, University of Allahabad, Allahabad, Uttar Pradesh, India

Keywords:

Macrocyclic Ligands, Organotellurium (II), XPS

Abstract

[(RR’Te)2.L1], [RR’Te.L2] and [RR’Te.L3] compounds (where R = R’ = C6H5CH2 ; p-MeOC6H4 ; R = p-MeOC6H4  & R’ = p-Me2NC6H4 ; R = p-EtOC6H4 & R’ = p-Me2NC6H4; R = R’ = C6H4C6H4) and  L= L1= 3, 6, 9, 12, 20, 23, 26, 29, 35, 36–decaazatricyclo[29.3.1.1] hexatriaconta-1(34), 14, 16, 18(36), 31(35), 32-hexaene-2, 13, 19, 30-tetraone; L2=3, 6, 9, 17, 20, 23, 29, 30- octaazatricyclo [23.3.1.1] triaconta-1 (28), 11, 13, 15(30), 25(29), 26-hexaene-2, 10, 16, 24–tetraone and L3= 3, 7, 15, 19, 25, 26–hexaazatricyclo[19.3.1.1]hexacosa-1(24), 9, 11, 13(26), 21(25), 22–hexaene–2, 8, 14, 20–tetraone have been synthesized and characterized by elemental analysis, molar conductance, I.R. and X-ray photoelectron spectra (XPS) data and an distorted octahedral geometry were established.

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[1]
Shishir Malviya, Abhishek Kumar, Rajesh Kumar Kushwaha, Shekhar Srivastava, " Synthesis and Characterization of [(RR’Te)2L] and [RR’Te.L] Compounds with Macrocyclic Ligands : A Photoelectron Spectroscopic Study, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 2, Issue 4, pp.517-524, July-August-2016.