Physico-Chemical Studies of Calcium Caproate after Addition of Amide Additive Using Ion-Selective Electrode

Authors

  • Dushyant Pareek  Department of Chemistry, S.D. Govt. College, Beawar, Rajasthan, India
  • Narendra Nirwan  Department of Chemistry, S.D. Govt. College, Beawar, Rajasthan, India
  • Chandresh Pareek  Department of Chemistry, S.D. Govt. College, Beawar, Rajasthan, India

Keywords:

Hydrophilic Oleomicelle, Ion-Selective Electrode, Lipophilic Hydromicelle, Ice-Berg, Palisade Layers

Abstract

EMF of the cell containing calcium caproate soaps solution in methanol-water solvent system waas measured with the aid of ion-selective electrode. The Critical Micelle Concentration of soap solutions was determined by graphical method. The effect of amide additives on CMC values of referred soap solution has been studied by using electrometric method with the aid of ion selective electrode. The values of free energy change are negative indicating the spontaneity of cell reaction and decreases with increasing soap concentration while increases with the increase methanol concentration in solvent mixture.

References

  1. Lehman, A.J. : Assoc. Food and Drug Officials, U.S. Quart. Bull., 15 (1951) 82-89.
  2. Bershold, E., Hoyer, H. and Rosenberg, G.V. : U.S., 2, Aug. 5 (1958)846, 330.
  3. Cunder, J. and Licata, F.J. : U.S., 2, Aug. 23 (1955) 716, 073.
  4. Ninich, A. and Levinson, H. : U.S., 2, March 25 (1941) 236, 296.
  5. Soc. Anon. Ghent. : Brit., March 21 (1962) 891, Neth. Appl. July 17 (1958) 858.
  6. Robert, A. : Fr., 2, Oct. 13 (1972) 123, 38,. Appl., Sept. 25 (1970) 7034, 744.
  7. Reynolds Maatschappij, N.V. : Neth., June 5 (1962) 101, Appl. May 5 (1956) 474.
  8. Instytul Mechaniki Precyzyjnej : Pol., Spt. 20 (1962) 46, Appl. Decl. Lpp. (1960) 092.
  9. Alvisatos, A.P. : Science, 271(1996) 933.
  10. Henglein, A. : Ber. Bunsenges. Phys. chem., 101 (1997) 1562.
  11. Kim, S.H., Medeiros-Ribeiro, G., Ohlberg, D.A., Williams, R.A. and Heath, Z.R. : J. Phys. chem. , 103 (1999) 10341.
  12. McConnel, W.P., Novak, J.P., Brousseav III, L.C, Fuierer, R.R., Tenent, R.C. and Feldhem, D.L. : J. Phys. Chem. B, 104 (2000) 8925.
  13. Pradhan, N., Pal A. and Pal, T. : Langmuir, 17 (2001) 1800.
  14. Mallick, K., Wong, Z.L. and Pal, T. : J. Photo Chem., Photobio. A, 140 (2001) 75.
  15. Varma, R.P. and Kumar, K.: Cellulose Chem. Technol., 9 (1975) 23-30.
  16. Mehta, V.P., Hasan, M., Mathur, S.P. and Rai, G.L. : Tenside Deterg., 16 (2) (1979) 79-80.
  17. Koga, Y., and Matuura : Mem. Fac. Sci. Kyushu Univ. Ser., C. 4 (1961) 1.
  18. Kagarise, R.E. : J. Phy. Chem., 59 (1955) 271.
  19. Mehrotra, K.N., Rajpurohit, M.S. and Godara, V.K. : J. Macromol. Sci. Chem. 19 (1983) 181.
  20. Mehrotra, K.N. and Saroha, S.P.S. : J. Ind. Chem. Soc., 56 (1979) 466.
  21. Duval, C., Lacomte, J. and Douville, F. : Ann. Phys., 17 (1942) 95.
  22. Varma, R.P. and Kumar, K. : J. Indian Chem. Soc. Vth, (1978) 675.
  23. L.C. Heda, D. Pareek, C. Pareek and S. Mosalpuri, Tenside Surf. Det. 45 (2005) 268-271
  24. Vesely, J., Weiss, D. and Stulic, K.: Analysis with Ion Selective Electrodes, Page - 15 - 6, Edit. by John Wiley & Sons (1978).
  25. Saleh, M. B. : Ind. J. Chem., 30A, (1991) 444-446.
  26. Tiwari, K. K. and Chattopadhyaya, M.C. : Ind. J. Chem., 40 A (2001) 619-621.
  27. Kobayashi, T., Kataoka, M. and Kambara, T. : Talanta., 27 (1980) 253-256.
  28. Frank, H.S. and Evans, M.W. : J. Phys. Chem, 13, 507 (1945).
  29. Goddard, E.D. and Benson, G.C. Can. J. Chem., 35 978 (1957).
  30. Goddard, E.D. ; Hoeve, C.A. J. and Benson, G.C. : J. Phys. Chem. 61, 593 (1957).
  31. Xue-Gog Lei, Chinese Journal of Chemistry, 10(3) (2010) 185-192
  32. Alam M.S.,Kumar N.,Vijaykumar V., Journal of Molecular Vol-XI (2014) 58-61
  33. Pareek D., Pareek C., Nirwan N., IJSRSET, Vol. 1, Jan. Feb. 2015 (1) 1, 435-444.
  34. Pareek D., Pareek C., Nirwan N., IJSRST, Vol. 1, July-August 2015(1)3 , 231-240.

International Journal of Scientific Research in Science, Engineering and Technology

Downloads

Published

2016-10-30

Issue

Volume 2, Issue 5, September-October-2016

Section

Research Articles

License

Copyright (c) IJSRSET

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
Dushyant Pareek, Narendra Nirwan, Chandresh Pareek "Physico-Chemical Studies of Calcium Caproate after Addition of Amide Additive Using Ion-Selective Electrode" International Journal of Scientific Research in Science, Engineering and Technology (IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 2, Issue 5, pp.599-610, September-October-2016.