Spectroscopic and Biological Studies of 3,5-Dichlorosalicylaldehyde-3-Aminopyridine Schiff Base and their Tellurium(IV) Complexes

Authors

  • Gobind Goyat  Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India
  • Anju Malik  Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India
  • Vikas  Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India
  • K. K. Verma  Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India
  • Sapana Garg  Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India

Keywords:

3,5-Dichlorosalicylaldehyde, Bidentate Schiff base, Tellurium(IV) Complexes

Abstract

3,5-Dichlorosalicylaldehyde react with 3-aminopyridine to gives monobasic ON bidentate Schiff base ligand (3-APY-{3,5-ClSalH}). TeCl4, ArTeCl3 and Ar2TeCl2: where Ar = 4-methoxyphenyl, 4-hydroxyphenyl, 3-methyl-4-hydroxyphenyl, react with above Schiff base leads to seven new complexes: having formula [TeCl3(3-APY-{3,5-ClSal})], [ArTeCl2(3-APY-{3,5-ClSal})] and [Ar2TeCl(3-APY-{3,5-ClSal})]. The purity of these compounds was estimated by TLC technique, while their structures were supported by elemental analyses, conductance measurement and spectroscopic methods such as 1HNMR, infrared spectra giving pentacoordinated tellurium centre having ? – trigonal bipyramidal geometry. Also, Schiff base ligand and some of their tellurium(IV) complexes display biological activities in vitro against bacteria and fungii.

References

  1. Lei Shi, Hui- Ming Ge, Shu -Hua Tan, Huan- Qui Li, Yong-Chun Song, Hai -Liang Zhu and Ren -Xiang Tan, Eur. J. Med. Chem., 2007, 42, 558-564.
  2. Chetana P R, Sahana S, Policegoudra R S and Aradhya S, Ind. J. Pharm. Sci. Res., 2016, 6(1), 18-26.
  3. Canpolat E, Kaya M, Russ. J. Coord. Chem., 2005, 31(11), 790-794.
  4. Booysena I N, Maikoa S, Akermana M P, Xulua B and Murno O, J. Coord. Chem., 2013, 66(20), 3673-3685.
  5. Barwiolek M, Szlyk E, Surdykowski A and Wojtczak A, Dalton Trans., 2013, 42, 11476-87.
  6. Fernandez G M, Portilla F R, Garcoa B Q, Toscano R A and Salcedob R, J. Mol. Struct., 2001 56(1-3), 197-207.
  7. Sridhar S K, Saravanan M and Ramesh A, Eur. J. Med. Chem., 2001, 36, 615-625.
  8. Mladenova R, Ignatova M, Manolova N, Petrova T and Rashkov I, Eur. Polym. J., 2002, 38, 989-999.
  9. Panneerselvem P, Nair R R, Vijayalakshmi G, Subramanian E H and Sridhar S K, Eur. J. Med. Chem., 2005, 40, 225-229.
  10. Walsh O M, Meegan M J, Prendergast R M and Nakib T A, Eur. J. Med. Chem., 1996, 31, 989-1000.
  11. Pandeya S N, Sriram D, Nath G and DeClercq E, Eur. J. Pharm., 1999, 9, 25-31.
  12. Pandeya S N, Sriram D, Nath G and DeClercq E, Pharm. Acta Helv. 1999, 74, 11-17.
  13. Ramesh R and Maheswaran S, J. Inorg. Biochem., 2003, 96, 457-462.
  14. Liu M C, Lin T S and Sartorelli A C, J. Med. Chem., 1992, 35, 3672-3677.
  15. Hodnett E M and Dunn J W, J. Med. Chem., 1970, 13, 768-770.
  16. Gupta V, Singhand S and Gupta Y K, Res. J. Chem. Sci. 2013, 3(9), 26-29.
  17. Felton L C and Brewer J H, Science 1947, 105, 409-410.
  18. Byoke M S and Gulya A P, Pharm. Chem. J., 2005, 39, 30-32.
  19. Jeewoth T, Bhowon M G and Li Kam Wah H, Trans. Met. Chem., 1999, 24, 445-448.
  20. Cimerman Z, Galic N and Bosner B, Anal. Chim. Acta, 1997, 343, 145.
  21. Dubey P K and Ratnam C V, Proc. Indian Acad. Sci., 1977, 85A, 204.
  22. Cimerman Z, Galesic N and Bosner B, J. Mol. Stru., 1992, 274, 131.
  23. Cushman M, Wong W C and Bacher A, J. Chem. Soc.Perkin Trans, 1986, 1, 1043.
  24. Mellor J M, Stibbard J H A and Rawlins M F, J. Chem. Soc. Chem. Comm., 1978, 557.
  25. Zecchini G P, Torrini I and Paradisi M P, J. Heterocyclic Chem., 1985, 22 1061.
  26. Press J B, Hofmann C M, Wiegand G E and Safir S R, J. Heterocyclic Chem., 1982, 19, 391.
  27. Essassi E M, Zniber R, Bernardini A and Viallefont P, J. Heterocyclic Chem., 1983, 20, 1015.
  28. Robertson D W, Beedle E E, Krushinski J H, Pallock G D, Wilson H, Wyss V L and Hayes J S, J. Med. Chem., 1985, 28, 717.
  29. Israel M and Jones L C, J. Heterocyclic. Chem., 1973, 10, 201.
  30. Middleton R W and Wibberley D G, J. Heterocyclic Chem., 1980, 17, 1757.
  31. Goyat G, Garg S and Verma K K, Chem. Sci. Trans., 2016, 5(2), 479-487.
  32. Goyat G, Garg S and Verma K K, Res. J. Pharm. Biol. Chem. Sci., 2016, 7(2), 869-877.
  33. Goyat G, Malik A, Garg S and Verma K K, Int. J. Chem. Sci., 2016, 14(3), 1498-1510.
  34. Goyat G, Malik A, Garg S and Verma K K, J. Chem. Pharm. Res., 2016, 8(4), 218-223.
  35. Goyat G, Malik A, Garg S and Verma K K, Int. J. Chem. Sci., 2016, 14(1), 387-398.
  36. Goyat G, Malik A, Garg S and Verma K K, Der Pharma Chemica, 2016, 8(2), 198-203.
  37. Malhotra K C and Paul K K, Curr. Sci., 1969, 38, 266.
  38. Peirier M and Vincontini, Anal. Acad. Brazil Cinene, 1971, 43, 119.
  39. Aynsley E E and Campbell W A, J. Chem. Soc., 1958, 3290.
  40. Wynne K J and Pearson P S, Inorg. Chem., 1971, 10, 2735.
  41. Wynne K J and Pearson P S, J. Chem. Soc. Commun., 1970, 556.
  42. Wynne K J, Clark A J and Berg M, J. Chem. Soc. Dalton, 1972, 2370.
  43. Clark E R, Collet A J and Naik D G, J. Chem. Soc. Dalton, 1973, 1961.
  44. Berg M C, Diss. Abstr. Int., 1972, 33, 2982.
  45. Srivastava T N, Singh M and Singh H B, Indian J. Chem., 1982, 21A, 307.
  46. Srivastava T N, Srivastava R C and Srivastava M, Indian J. Chem., 1982, 21A, 539.
  47. Srivastava T N, Srivastava R C and Srivastava V K, J. Indian Chem. Soc., 1983, 60, 891.
  48. Garad M V, Polyhedron, 1985, 4, 1353.
  49. Verma K K and Reena, Synth. React. Inorg. Met. -Org. Chem., 1999, 29, 499-512.
  50. Verma K K, Dahiya R and Soni D, Synth. React. Inorg. Met. -Org. Chem., 1999, 29, 1033-1052.
  51. Verma K K and Dahiya R, Synth. React. Inorg. Met. -Org. Chem., 1999, 29, 1299-1314.
  52. Verma K K and Reena, Phosphorus, Sulfur and Silicon and the Related Elements, 1999, 148, 227-234.
  53. Verma K K and Seema, Int. J. Chem. Sci., 2008, 6, 371-380.
  54. Malik A, Verma K K and Garg S, Res. J. Pharm. Biol. Chem. Sci., communicated.
  55. Srivastava S, Soni D K and Gupta H S, J. Indian Chem. Soc., 1996, 73, 255.
  56. Narwal J K, Chhabra S, Malik R K, Garg S and Verma K K, Oriental J. Chem., 2013, 29, 1339-1349.
  57. Chhabra S and Verma K K, J. Chem. Pharm. Res., 2010, 2, 569-575.
  58. Vogel A I, A Test Book of Organic Chemistry, 3rd Edn., Longman: London, 1975.
  59. Weissberger A, Ed., Technique of Organic Chemistry, Vol. 7, 2nd Edn., Interscience Publishers, Inc.: N. Y., 1967.
  60. Morgan G T and Kellet R E, J. Chem. Soc., 1926; 1080.
  61. Petragnani N and Stefani H A, Tellurium in Organic Chemistry, 2nd Edn., Academic Press: London, 2007, 76.
  62. Bergman J, Tetrahedron, 1972, 28, 3323.
  63. Khandelwal B L, Kumar K and Berry F J, Inorg. Chim. Acta, 1981, 99, 135-137.
  64. Khandelwal B L, Kumar K and Raina K, Synth. React. Inorg. Met. -Org. Chem., 1981, 11, 65-78.
  65. Abdel-Latif S A, Hassib H B and Issa Y M, Spectrochim. Acta(A) 2007, 67, 950-957.
  66. Geary W J, Coord. Chem. Rev., 1971, 7, 81-122.
  67. Greenwood N N, Straughan B P and Wilson A E, J. Chem. Soc. A, 1968, 2209.
  68. Srivastava K P, Singh A and Singh S K, Journal of Applied Chemistry, 2014, 7(4), 16-23.
  69. Dharmaraj N, Trans. Metal Chem., 2001, 26, 105-109.
  70. Verma K K, Soni D and Verma S, Phosphorus, Sulfur and Silicon, 2000, 166(1), 231-241.
  71. Pant B C, Mc Whinnie W R and Dance N S, J. Organmetal Chem., 1973, 63, 305-310.
  72. Kohawole G A and Patel K S, J. Chem. Soc., Dalton Trans., 1981, 1241.
  73. Gluvchinsky P and Moeler G M, Spectrochim. Acta., 1973, 32, 1615.
  74. Srivastava T N, Singh J D, Indian J. Chem., 1987, 26A, 260.
  75. Chauhan S, Garg S and Verma K K, Chem. Sci. Trans., 2016, 5(2), 431-441.
  76. Kulkarni Y D, Srivastava S, Abdi S H R and Athar M, Synth React Inorg Met Org Chem., 1985, 15(8), 1043-1059.
  77. Khera B, Sharma A K and Kaushik N K, Polyhedron, 1983, 2, 1177.
  78. Joshi K R, Rojivadiya A J and Pandya J H, Int. J. Inorg. Chem., 2014, 10, 1155.

International Journal of Scientific Research in Science, Engineering and Technology

Downloads

Published

2018-02-28

Issue

Volume 4, Issue 1, January-February-2018

Section

Research Articles

License

Copyright (c) IJSRSET

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
Gobind Goyat, Anju Malik, Vikas, K. K. Verma, Sapana Garg "Spectroscopic and Biological Studies of 3,5-Dichlorosalicylaldehyde-3-Aminopyridine Schiff Base and their Tellurium(IV) Complexes" International Journal of Scientific Research in Science, Engineering and Technology (IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 4, Issue 1, pp.755-762, January-February-2018.