Micellar Studies of Calcium Soaps Using Ion-Selective Electrode

Authors

  • Dushyant Pareek  Department of Chemistry, S.D. Govt. College, Vidya Nagar, Beawar, Rajasthan, India
  • Chandresh Pareek  Department of Chemistry, S.D. Govt. College, Vidya Nagar, Beawar, Rajasthan, India
  • Narendra Nirwan  Department of Chemistry, S.D. Govt. College, Vidya Nagar, Beawar, Rajasthan, India

Keywords:

Ion-Selective Electrode, Micellization, EMF, Hydrophilic Oleomicelle, Lipophilic Hydromicelle

Abstract

Calcium soaps of caproic and caprylic acids were prepared and a cell was set up for the measurement of EMF of the cell containing referred soap solutions in methanol water solvent system with the aid of Ion-Selective Electrode. The Critical Micelle Concentration of soap solutions was determined by plotting the electromotive force of the cell against soap concentration. The Critical Micelle Concentration of these soap solutions varies with increase in chain length of the fatty acids in the soap. The energetic studies of the system have been carried out from the electromotive force values of the cell containing soap solution to ascertain the chain length compatibility and agglomeration profile. The values of free energy change are negative indicating the spontaneity of cell reaction and decreases with increasing soap concentration while increases with the increase methanol concentration in solvent mixture.

References

  1. Lehman, A.J. : Assoc. Food and Drug Officials, U.S. Quart. Bull., 15 (1951) 82-89.
  2. Bershold, E., Hoyer, H. and Rosenberg, G.V. : U.S., 2, Aug. 5 (1958) 846, 330.
  3. Cunder, J. and Licata, F.J. : U.S., 2, Aug. 23 (1955) 716, 073.
  4. Ninich, A. and Levinson, H. : U.S., 2, March 25 (1941) 236, 296.
  5. Soc. Anon. Ghent. : Brit., March 21 (1962) 891, Neth. Appl. July 17 (1958) 858.
  6. Robert, A. : Fr., 2, Oct. 13 (1972) 123, 38,. Appl., Sept. 25 (1970) 7034, 744.
  7. eynolds Maatschappij, N.V. : Neth., June 5 (1962) 101, Appl. May 5 (1956) 474.
  8. Instytul Mechaniki Precyzyjnej : Pol., Spt. 20 (1962) 46, Appl. Decl. Lpp. (1960) 092.
  9. Alvisatos, A.P. : Science, 271(1996) 933.
  10. Henglein, A. : Ber. Bunsenges. Phys. chem., 101 (1997) 1562.
  11. Kim, S.H., Medeiros-Ribeiro, G., Ohlberg, D.A., Williams, R.A. and Heath, Z.R. : J. Phys. chem. , 103 (1999) 10341.
  12. McConnel, W.P., Novak, J.P., Brousseav III, L.C, Fuierer, R.R., Tenent, R.C. and Feldhem, D.L. : J. Phys. Chem. B, 104 (2000) 8925.
  13. Pradhan, N., Pal A. and Pal, T. : Langmuir, 17 (2001) 1800.
  14. Mallick, K., Wong, Z.L. and Pal, T. : J. Photo Chem., Photobio. A, 140 (2001) 75.
  15. Varma, R.P. and Kumar, K.: Cellulose Chem. Technol., 9 (1975) 23-30.
  16. Mehta, V.P., Hasan, M., Mathur, S.P. and Rai, G.L. : Tenside Deterg., 16 (2) (1979) 79-80.
  17. Koga, Y., and Matuura : Mem. Fac. Sci. Kyushu Univ. Ser., C. 4 (1961) 1.
  18. Kagarise, R.E. : J. Phy. Chem., 59 (1955) 271.
  19. Mehrotra, K.N., Rajpurohit, M.S. and Godara, V.K. : J. Macromol. Sci. Chem. 19 (1983) 181.
  20. Mehrotra, K.N. and Saroha, S.P.S. : J. Ind. Chem. Soc., 56 (1979) 466.
  21. Duval, C., Lacomte, J. and Douville, F. : Ann. Phys., 17 (1942) 95.
  22. Varma, R.P. and Kumar, K. : J. Indian Chem. Soc. Vth, (1978) 675.
  23. Vesely, J., Weiss, D. and Stulic, K.: Analysis with Ion Selective Electrodes, Page - 15 - 6, Edit. by John Wiley & Sons (1978).
  24. Saleh, M. B. : Ind. J. Chem., 30A, (1991) 444-446.
  25. Tiwari, K. K. and Chattopadhyaya, M.C. : Ind. J. Chem., 40 A (2001) 619-621.
  26. Kobayashi, T., Kataoka, M. and Kambara, T. : Talanta., 27 (1980) 253-256.
  27. Vesely, J., Weiss, D. and Stulic, K. : Analysis with Ion Selective Electrodes, Page - 23, Edit. by John Wiley & Sons (1978).
  28. Laing, M.E. : J. Chem. Soc., 113 (1918) 435.
  29. Varma, R.P. and Bahadur, P. : Cellulose Chem. Technol., 8 (1974) 27-37.
  30. Schulman, J.H. and Riley, D.P. : J. Colloid. Sci., 3 (1948) 383.
  31. Mehrotra, K.N. and Bhargava, S.C. : Z. Physik. Chem., 233 (1966) 97-102.
  32. Jones, G. and Bick Ford, C. F. : J. Am. Chem. Soc., 56 (1934) 604.
  33. Mehrotra, K.N. and Bhargava, S.C. : Bull, Chem. Soc. Japan, 405 (1967) 1255.
  34. Prakash, S., Icinaporia, F.M. and Pandey, J.D. : J. Phys. Chem., 58 (1964) 3078.
  35. Upadhyaya, S. K. : Ind. J. Chem., 39A (2000) 537-540.
  36. Nandi, N. : Ind. J. Chem., 37A (1998) 114-117.
  37. Mehrotra, K.N. and Bhargava, S.C. : Kolloid –Zeitschrift and Zeitschrift Polymer, Band 210, Heft 2, Seite (1966) 138-143.
  38. L.C. Heda, D. Pareek, C. Pareek and S. Mosalpuri, Tenside Surf. Det. 45 (2005) 268-271
  39. Xue-Gog Lei, Chinese Journal of Chemistry, 10(3) (2010) 185-192
  40. M.S. Alam, V. Naresh Kumar, N Vijaykumar, Journal of Molecular Vol-XI (2014) 58-61

International Journal of Scientific Research in Science, Engineering and Technology

Downloads

Published

2015-02-26

Issue

Volume 1, Issue 1, January-February-2015

Section

Research Articles

License

Copyright (c) IJSRSET

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
Dushyant Pareek, Chandresh Pareek, Narendra Nirwan "Micellar Studies of Calcium Soaps Using Ion-Selective Electrode " International Journal of Scientific Research in Science, Engineering and Technology (IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 1, Issue 1, pp.435-444, January-February-2015.