Effect of UV-curing conditions on the cationic polymerization kinetics of vinyl ether monomers

Authors

  • Duong Hong Quyen  Hanoi University of science and technology, Hanoi, Vietnam
  • Hoang Thi Kieu Nguyen  Hanoi University of science and technology, Hanoi, Vietnam

DOI:

https://doi.org/10.32628/IJSRSET2293149

Keywords:

Cationic Initiator, Polymerization, UV-Curing, Divinyl Ether

Abstract

In this study, the performance of a new triarylsulfonium photoinitiator in the initiation of cationic polymerization of vinyl monomers was investigated by infrared spectroscopy (IR). The effect of the emission spectrum of light sources on the kinetics of the curing process was examined. The results indicate that the light source characterized by a total overlap of its emission spectrum with the photoinitiator absorption spectrum is the best system for effective cure. In the case of smaller overlap of spectrums, the conversion degree and the rate are lower. Nevertheless, it is easy to regulate by extending the energy of the emitted light. At the UVB light source, the maximal conversion degree is 71.8%, with the polymerization rate of 1.68 s-1, which is faster than the corresponding free-radical photopolymerization of acrylic monomers.

References

  1. M. Sangermano. J. Photopolym. Sci. Technol., 2019, 32(2), ISSN: 09149244
  2. E. Hola et al., 2020. RSC Adv., 2020, 10(13), ISSN:
  3. M. Sangermano, 2012. Pure Appl. Chem, 2012, 84(10), ISSN: 13496336
  4. M. S. Malik, S. Schlögl, M. Wolfahrt, and M. Sangermano, 2020. Polymers (Basel)., 2020, 12(9), ISSN: 20734360
  5. J. Ortyl and R. Popielarz, 2012. Polimery/Polymers, 2012, 57 (7-8), ISSN: 00322725
  6. C. Mendes-Felipe, J. Oliveira, I. Etxebarria, J. L. Vilas-Vilela, and S. Lanceros-Mendez, 2019. Adv. Mater. Technol., 2019, 4(3), ISSN: 2365709X
  7. Evgueni Kirillov, Konstantin Rodygin, Valentine Ananikov. 2020. European Polymer Journal, 2020, 136, ISSN: 00143057
  8. J. Kindernay, A. Blažková, J. Rudá, V. Jančovičová, and Z. Jakubíková, 2002. J. Photochem. Photobiol. A Chem., 2002, 151(1-3), ISSN: 10106030
  9. V. Jančovičová, M. Mikula, B. Havlínová, and Z. Jakubíková, 2013. Prog. Org. Coatings, 2013, 76(2-3), ISSN: 03009440
  10. V. Jančovičová, J. Kindernay, Z. Jakubíková, and I. Mrlláková. 2007. Chem. Pap., 2007, 61(5), ISSN: 03666352

International Journal of Scientific Research in Science, Engineering and Technology

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Published

2022-06-30

Issue

Volume 9, Issue 3, May-June-2022

Section

Research Articles

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This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
Duong Hong Quyen, Hoang Thi Kieu Nguyen "Effect of UV-curing conditions on the cationic polymerization kinetics of vinyl ether monomers " International Journal of Scientific Research in Science, Engineering and Technology (IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 9, Issue 3, pp.491-492, May-June-2022. Available at doi : https://doi.org/10.32628/IJSRSET2293149