Assessment of Selected Heavy Metals Levels in Soil from the Athi-Thwake River Catchment Area, Makueni County, Kenya
DOI:
https://doi.org/10.32628/IJSRSET25121275Keywords:
Heavy metals, soil, seasonal variation, Athi-Thwake River catchment, KenyaAbstract
This study assessed the levels of lead, zinc, copper, chromium, cadmium, nickel, iron, and manganese in soil samples from ten specific sites within the Athi-Thwake River catchment area in November 2021 and January 2022, representing the wet and dry seasons respectively in Makueni County. The samples were analyzed using an Atomic Absorption Spectrophotometer (AAS) and data by IBM SPSS 20. The metal levels ranged from 0.10 ± 0.03 mg/kg - 188.02 ± 3.69 mg/kg. In the dry season, the order of metal levels was iron > lead > zinc > manganese > copper > chromium > cadmium > nickel these values were compared with the World Health Organization (WHO) recommended limits for soil quality. Zinc and copper levels were within the WHO limits of 5.0 mg/kg and 10 mg/kg, respectively. However, the mean levels of lead, cadmium, nickel, iron, and manganese in both the wet and dry seasons showed significant differences (p<.05) and exceeded WHO limits of 0.1 mg/kg, 0.1 mg/kg, 0.003 mg/kg, 0.05 mg/kg, 55 mg/kg, and 0.5 mg/kg, respectively, while copper and chromium showed no statistical significance (p>.05). The study revealed the importance of conducting thorough soil analysis, specifically focusing on heavy metals in the ten selected sites. The study showed the presence of high levels of these metals in soil in the catchment area and this could be impacting negatively on the ecosystem health of the area.
Downloads
References
D. C. Adriano, Trace Elements in Terrestrial Environments. New York, NY: Springer New York, 2001. doi: 10.1007/978-0-387-21510-5.
G. S. Senesi, ), Baldassarre G. ,., N. Senesi, and B. Radina, “Trace element inputs into soils by anthropogenic activities and implications for human health. Chemosphere,” no. 39, pp. 343–377, 1999.
M. Raghunath et al., “Carboxy-terminal conversion of profibrillin to fibrillin at a basic site by PACE/furin-like activity required for incorporation in the matrix,” J. Cell Sci., vol. 112, no. 7, pp. 1093–1100, Apr. 1999, doi: 10.1242/jcs.112.7.1093.
B. Wei and L. Yang, “A review of heavy metal contaminations in urban soils, urban road dusts and agricultural soils from China,” Microchem. J., vol. 94, no. 2, pp. 99–107, Mar. 2010, doi: 10.1016/j.microc.2009.09.014.
A. Facchinelli, E. Sacchi, and L. Mallen, “Multivariate statistical and GIS-based approach to identify heavy metal sources in soils,” Environ. Pollut., vol. 114, no. 3, pp. 313–324, Oct. 2001, doi: 10.1016/S0269-7491(00)00243-8.
X. Chen and V. Achal, “Biostimulation of carbonate precipitation process in soil for copper immobilization,” J. Hazard. Mater., vol. 368, pp. 705–713, Apr. 2019, doi: 10.1016/j.jhazmat.2019.01.108.
P. A. Kabata and H. Pendias, “Trace Elements in Soils and Plants. 3rd Edition, CRC Press, .,” p. 403, 2001.
E. Wang et al., “The uncertainty of crop yield projections is reduced by improved temperature response functions,” Nat. Plants, vol. 3, no. 8, p. 17102, Jul. 2017, doi: 10.1038/nplants.2017.102.
L. Pan, J. Ma, X. Wang, and H. Hou, “Heavy metals in soils from a typical county in Shanxi Province, China: Levels, sources and spatial distribution,” Chemosphere, vol. 148, pp. 248–254, Apr. 2016, doi: 10.1016/j.chemosphere.2015.12.049.
Y. Liu, J. Zhang, and T. Hu, “The impact of soil pH on the availability of soil nutrients and the growth of plants. Environmental Science and Pollution Research,” vol. 17, no. 3, pp. 726–735, 2010.
J. O. Nyaboke, “Assessment of heavy metal pollution in the sediments of River Migori, Kenya. Journal of Environmental Science, Toxicology, and Food Technology,” p. 7(2), 45–52, 2013.
J. Maghanga K., J. Lagat K., and R. Ong’anyi, “Impacts of irrigation on water quality in river ecosystems: A case study of the river Isiukhu in Kakamega County, Kenya. International Journal of Current Research and Review.,” p. 4(9), 22–27, 2012.
W. M. Nyairo, P. O. Okemo, and W. Matini, “Heavy metal contamination of water, soil, and sediments in the Nairobi River basin, Kenya. African Journal of Environmental Science and Technology.,” p. 9(3), 210–217, 2015.
S. Omwamo, J. O. Lalah, and S. O. Wandiga, “Sources, distribution, and impacts of heavy metals in water, soil, and sediments of Lake Victoria basin, Kenya. Environmental Science and Pollution Research.,” p. 18(6), 1166–1174, 2011.
M. S. Kariuki, A. A. Deborah, G. N. K. , Joyce, and P. O. O. John, “Determination of Physical Properties of Soil from the Athi - Thwake River Catchment Area, Makueni County, Kenya,” Int. J. Res. Sci. Innov., vol. 13, no. 11.
“WHO.” 2010.
“KEBS.” 2014.
P. Sardar, R. Nairooz, and G. Pekler, “Letter by Sardar et al Regarding Article, ‘Optimal Duration of Dual Antiplatelet Therapy After Drug-Eluting Stent Implantation: A Randomized, Controlled Trial,’” Circulation, vol. 130, no. 18, Oct. 2014, doi: 10.1161/CIRCULATIONAHA.113.006936.
H. R. Gebeyehu and L. D. Bayissa, “Levels of heavy metals in soil and vegetables and associated health risks in Mojo area, Ethiopia,” PLOS ONE, vol. 15, no. 1, p. e0227883, Jan. 2020, doi: 10.1371/journal.pone.0227883.
L. T. Ogundele, I. A. Adejoro, and P. O. Ayeku, “Health risk assessment of heavy metals in soil samples from an abandoned industrial waste dumpsite in Ibadan, Nigeria,” Environ. Monit. Assess., vol. 191, no. 5, p. 290, May 2019, doi: 10.1007/s10661-019-7454-8.
“WHO,” 2006.
M. O. Barkett and E. Akün, “Heavy metal contents of contaminated soils and ecological risk assessment in abandoned copper mine harbor in Yedidalga, Northern Cyprus,” Environ. Earth Sci., vol. 77, no. 10, p. 378, May 2018, doi: 10.1007/s12665-018-7556-6.
T. B. Asfaw, T. M. Tadesse, and A. M. Ewnetie, “Determination of Total Chromium and Chromium Species in Kombolcha Tannery Wastewater, Surrounding Soil, and Lettuce Plant Samples, South Wollo, Ethiopia,” Adv. Chem., vol. 2017, pp. 1–7, Sep. 2017, doi: 10.1155/2017/6191050.
M. Borah,), M. Prashanthi Devi, and Bhuyan, B., “Assessment of soil heavy metal pollution and associated ecological risk in the mid-channel bar of the Damodar River, India.,” no. 604, 2018, doi: https://doi.org/10.1007/s10661-018-7010-0.
J. Marković et al., “Cadmium retention and distribution in contaminated soil: effects and interactions of soil properties, contamination level, aging time and in situ immobilization agents,” Ecotoxicol. Environ. Saf., vol. 174, pp. 305–314, Jun. 2019, doi: 10.1016/j.ecoenv.2019.03.001.
A. S. El-Hassanin, M. R. Samak, G. N. Abdel-Rahman, Y. H. Abu-Sree, and E. M. Saleh, “Risk assessment of human exposure to lead and cadmium in maize grains cultivated in soils irrigated either with low-quality water or freshwater,” Toxicol. Rep., vol. 7, pp. 10–15, 2020, doi: 10.1016/j.toxrep.2019.11.018.
Stearns J. C. ,., S. Shah, and B. R. Glick, “Increasing Plant Tolerance to Metals in the Environment. In Phytoremediation:,” pp. 15–26, 2007.
X. Ding, Li, Y. and J. Qin, “Heavy metal concentrations in soil and ecological risk assessment in the vicinity of Tianzhu Industrial Park, Qinghai-Tibet Plateau,” no. 431, p. 189, 2017.
X. Xu, C. Chen, P. Wang, R. Kretzschmar, and F.-J. Zhao, “Control of arsenic mobilization in paddy soils by manganese and iron oxides,” Environ. Pollut., vol. 231, pp. 37–47, Dec. 2017, doi: 10.1016/j.envpol.2017.07.084.
Downloads
Published
Issue
Section
License
Copyright (c) 2025 International Journal of Scientific Research in Science, Engineering and Technology

This work is licensed under a Creative Commons Attribution 4.0 International License.